128796-44-1

Upstream product

• 26562-17-4 {2,4,6-(CH3)3C6H2}2Hg 
• 5980-97-2 mesitylboronic acid 
• 546-67-8 lead(IV) tetraacetate 
• 5806-59-7 mesityllithium 

Downstream Products

• 1415575-76-6 C₂₄H₂₅F₃O₂S 
• 1415575-79-9 C₂₃H₂₄F₃NO₂S 
• 1415575-86-8 C₂₅H₂₇F₃O₂S 
• 1415575-88-0 C₂₄H₂₆F₃NO₂S 

Relevant academic research and scientific papers

HERBICIDE COMPOSITION

There is provided a herbicidal composition containing a cyclohexanone compound represented by Formula (I) and at least one compound selected from Group A. Group A: consisting of benoxacor, cloquintocet-mexyl, cyometrinil, dichlormid, fenchlorazole-ethyl,

Untersuchungen an Arylbleitriacetaten. Roentgenstrukturanalyse von 2-Methylphenyl- und 2-Chlorophenylbleitriacetat

The crystal structures of 2-XC6H4Pb(OAc)3 (X = CH3, Cl; OAc = OOCCH3) have been determined by X-ray diffraction.Both compounds are isostructural and crystallize as triclinic, space group P.They consist of monomers, the seven-coordinated central atom being in a distorted pentagonal-bipyramidal environment with five O atoms of the three unsymmetrically chelating carboxylate groups in equatorial positions, and one O and one C(aryl) atom in axial positions.IR, 1H, 13C and 207Pb NMR spectroscopic data of these and other monoaryllead triacetates are reported, and similar structures with seven-coordinated lead are inferred.Weak coordination of Y to Pb is discussed to exist possibly in 2-YC6H4Pb(OAc)3 (Y = F, Cl, OCH3).

Reaction of Arylboronic Acids and their Derivatives with Lead Tetra-acetate. The Generation of Aryl-lead Triacetates, and meta- and para-Phenylenebis(lead triacetate), in situ for Electrophilic Arylation

Arylboronic acids and some of their derivatives have been found to undergo a rapid boron-lead exchange with lead tetra-acetate.In the presence of a catalytic amount of mercury(II) acetate, the reaction produces mainly the aryl-lead triacetate, and it has been developed as a convenient method for in situ generation of these useful electrophilic C-arylating reagents.The reaction allows the generation for the first time of meta- and para-phenylenebis(lead triacetate), compounds which behave as meta- and para-phenylene dication equivalents.