128815-38-3Relevant articles and documents
Metal-free n -arylation of secondary amides at room temperature
Tinnis, Fredrik,Stridfeldt, Elin,Lundberg, Helena,Adolfsson, Hans,Olofsson, Berit
supporting information, p. 2688 - 2691 (2015/06/16)
The arylation of secondary acyclic amides has been achieved with diaryliodonium salts under mild and metal-free conditions. The methodology has a wide scope, allows synthesis of tertiary amides with highly congested aryl moieties, and avoids the regioselectivity problems observed in reactions with (diacetoxyiodo)benzene.
Reductive couplings of acid chlorides mediated by SmI2
Collin,Dallemer,Namy,Kagan
, p. 7407 - 7410 (2007/10/02)
Reductive couplings of acid chlorides and of acid chlorides with aldehydes or ketones in presence of an excess of SmI2 produce ketones in moderate to good yields.