128848-45-3

Basic information

• Product Name: phenyl 4,6-O-benzylidene-2,3-di-O-trimethylsilyl-1-thio-β-D-glucopyranoside
• Synonyms: phenyl 4,6-O-benzylidene-2,3-di-O-trimethylsilyl-1-thio-β-D-glucopyranoside
• CAS NO: 128848-45-3
• Molecular Weight: 504.795
• Mol File: 128848-45-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenyl 4,6-O-benzylidene-2,3-di-O-trimethylsilyl-1-thio-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 4,6-O-benzylidene-2,3-di-O-trimethylsilyl-1-thio-β-D-glucopyranoside(128848-45-3)
• EPA Substance Registry System: phenyl 4,6-O-benzylidene-2,3-di-O-trimethylsilyl-1-thio-β-D-glucopyranoside(128848-45-3)

Safety Data

• Hazardous Substances Data: 128848-45-3(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 71676-30-7 (2R,4aR,6S,7R,8R,8aS)-2-Phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 

Downstream Products

• 128848-47-5 Acetic acid (2R,4aR,6R,7R,8S,8aR)-2-phenyl-6-trimethylsilanyl-7-trimethylsilanyloxy-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester 
• 77453-79-3 1,5-anhydro-4,6-O-benzylidene-2-deoxy-3-O-trimethylsilyl-D-arabinohex-1-enitol 
• 128848-46-4 (4,6-O-benzylidene-2-O-trimethylsilyl-α-D-glucopyranosyl)trimethylsilane 

Relevant articles and documents

A NOVEL 1,3 O -> C SILYL REARRANGEMENT IN CARBOHYDRATE CHEMISTRY: SYNTHESIS OF α-D-GLYCOPYRANOSYLTRIMETHYLSILANES

Reductive lithiation of 2-O-trimethylsilyl derivatives of phenyl thiogluco and -galactopyranosides gives rise to a 1,3 O -> C silyl migration leading to α-D-gluco and -galactopyranosyltrimethylsilanes in good yields.The expected β-elimination is observed