77453-79-3

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 63598-36-7 4,6-O-benzylidene-D-glucal 
• 71676-30-7 (2R,4aR,6S,7R,8R,8aS)-2-Phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 63598-38-9 1,5-anhydro-4,6-O-benzylidene-2-deoxy-D-ribo-hex-1-enopyranose 
• 77481-85-7 1,5-anhydro-3-O-benzoyl-4,6-O-benzylidene-2-deoxy-D-ribo-hex-1-enitol 
• 77453-77-1 1,5-anhydro-3-O-benzoyl-4,6-benzylidene-2-deoxy-D-arabino-hex-1-enitol 
• 128848-45-3 phenyl 4,6-O-benzylidene-2,3-di-O-trimethylsilyl-1-thio-β-D-glucopyranoside 

Downstream Products

• 127604-39-1 4,6-O-benzylidene-3-carboxy-2-deoxy-β-D-altrohexopyranosylamino-lactam 
• 127643-70-3 N-benzyl-2-carboxy-2-deoxy-β-D-altrohexopyranosylaminolactam 
• 127643-71-4 (3S,4R)-N-benzyl-3-hydroxymethyl-4-(1',3'-dihydroxyisopropoxy)-azetidinone 
• 127604-40-4 N-benzyl-4,6-O-benzylidene-2-carboxy-2-deoxy-β-D-altrohexopyranosylamino-lactam 

Relevant academic research and scientific papers

A NOVEL 1,3 O -> C SILYL REARRANGEMENT IN CARBOHYDRATE CHEMISTRY: SYNTHESIS OF α-D-GLYCOPYRANOSYLTRIMETHYLSILANES

Reductive lithiation of 2-O-trimethylsilyl derivatives of phenyl thiogluco and -galactopyranosides gives rise to a 1,3 O -> C silyl migration leading to α-D-gluco and -galactopyranosyltrimethylsilanes in good yields.The expected β-elimination is observed

Allylic Nucleophilic Substitution Reactions in Sugars. III. Uncatalysed Displacements in Hexamethylphosphoramide

The uncatalysed displacement of allylic benzoyloxy groups with azide in unsaturated sugars has been studied by using hexamethylphosphoramide as solvent.Tri-O-benzoylglycals and 4,6-O-benzylidene-3-O-benzoylglycals were investigated.The former gave rise to