128848-52-2Relevant academic research and scientific papers
Synthesis of an α-kojibiosyl substituted glycerol teichoic acid hexamer
Hogendorf, Wouter F.J.,Bos, Leendert J. Van den,Overkleeft, Herman S.,Codée, Jeroen D.C.,Marel, Gijsbert A. Van der
experimental part, p. 3668 - 3678 (2010/08/05)
In this paper the synthesis of an Enterococcus Faecalis teichoic acid (TA) hexamer is presented. The key kojibiosyl-glycerol phosphoramidite building block was obtained by condensation of thioglucose donors, provided with various protecting groups at the
A NOVEL 1,3 O -> C SILYL REARRANGEMENT IN CARBOHYDRATE CHEMISTRY: SYNTHESIS OF α-D-GLYCOPYRANOSYLTRIMETHYLSILANES
Pedretti, Valerie,Veyrieres, Alain,Sinay, Pierre
, p. 77 - 88 (2007/10/02)
Reductive lithiation of 2-O-trimethylsilyl derivatives of phenyl thiogluco and -galactopyranosides gives rise to a 1,3 O -> C silyl migration leading to α-D-gluco and -galactopyranosyltrimethylsilanes in good yields.The expected β-elimination is observed
