128966-03-0

Basic information

• Product Name: N-Adamantan-1-yl-2-(2-fluoro-phenoxy)-2-methyl-propionamide
• CAS NO: 128966-03-0
• Molecular Weight: 331.43
• Mol File: 128966-03-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-Adamantan-1-yl-2-(2-fluoro-phenoxy)-2-methyl-propionamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-Adamantan-1-yl-2-(2-fluoro-phenoxy)-2-methyl-propionamide(128966-03-0)
• EPA Substance Registry System: N-Adamantan-1-yl-2-(2-fluoro-phenoxy)-2-methyl-propionamide(128966-03-0)

Safety Data

• Hazardous Substances Data: 128966-03-0(Hazardous Substances Data)

Upstream product

• 54059-85-7 N-(1-Adamantyl)-2-brom-2-methylpropansaeureamid 
• 768-94-5 1-Adamantanamine 
• 367-12-4 2-fluorophenol 
• 85433-69-8 (1-Adamantyl)-3,3-dimethyl-2-aziridinon 

Relevant articles and documents

The Conversion of Phenols to Primary and Secondary Aromatic Amines via a Smiles Rearrangement

The conversion of phenols to 2-aryloxy-2-methylpropanamides (1) and the Smiles rearrangement of these to N-aryl-2-hydroxy-2-methyl propanamides are described; hydrolysis of the latter compounds yields anilines.The scope and limitations of reaction are discussed.Routes, some involving α-lactams, from phenols to N-substituted derivatives of (1) have been developed.Under the conditions of the Smiles rearrangement these secondary 2-methylpropanamides can form directly anilides, N-alkylanilines, or benzoxazinones.