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367-12-4

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367-12-4 Usage

Chemical Properties

Clear colourless to yellow liquid

Synthesis Reference(s)

Tetrahedron, 52, p. 23, 1996 DOI: 10.1016/0040-4020(95)00867-8Journal of the American Chemical Society, 103, p. 1964, 1981 DOI: 10.1021/ja00398a015

General Description

Liquid or crystalline solid melting at 14-16°C. Corrosive. Density 1.246 g / cm3.

Air & Water Reactions

Highly flammable.

Reactivity Profile

2-Fluorophenol reacts as a weak organic acid. May be incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction with bases. Such heating may initiate polymerization of the organic compound. Sulfonated very readily (for example, by concentrated sulfuric acid at room temperature). The reactions generate heat. Nitrated very rapidly, even by dilute nitric acid.

Health Hazard

ACUTE/CHRONIC HAZARDS: Toxic and irritant.

Purification Methods

Pass o-fluorophenol at least twice through a gas chromatographic column for small quantities; otherwise fractionally distil it under reduced pressure. [Beilstein 6 I 97, 6 IV 770.]

Check Digit Verification of cas no

The CAS Registry Mumber 367-12-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 3,6 and 7 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 367-12:
(5*3)+(4*6)+(3*7)+(2*1)+(1*2)=64
64 % 10 = 4
So 367-12-4 is a valid CAS Registry Number.
InChI:InChI=1/C6H5FO/c7-5-3-1-2-4-6(5)8/h1-4,8H

367-12-4 Well-known Company Product Price

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  • (Code)Product description
  • CAS number
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  • Detail
  • Alfa Aesar

  • (A14979)  2-Fluorophenol, 98%   

  • 367-12-4

  • 25g

  • 622.0CNY

  • Detail
  • Alfa Aesar

  • (A14979)  2-Fluorophenol, 98%   

  • 367-12-4

  • 100g

  • 1960.0CNY

  • Detail
  • Alfa Aesar

  • (A14979)  2-Fluorophenol, 98%   

  • 367-12-4

  • 500g

  • 8937.0CNY

  • Detail
  • Supelco

  • (442350)  2-Fluorophenol  analytical standard

  • 367-12-4

  • 000000000000442350

  • 573.30CNY

  • Detail

367-12-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Fluorophenol

1.2 Other means of identification

Product number -
Other names O-FLUOROPHENOL

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:367-12-4 SDS

367-12-4Relevant articles and documents

AROMATIC FLUORINE CHEMISTRY. PART 3. PREPARATION OF FLUOROPHENOLS VIA HYDROLYSIS OF CHLOROFLUOROBENZENES

Pews, R. G.,Gall, J. A.

, p. 377 - 380 (1990)

The 1,2-, 1,3-, and 1,4-fluorophenols have been prepared by a copper (e.g.CuO, CuSO4) catalyzed hydrolysis of chlorofluorobenzenes under conditions of controlled pH.

Photo-induced thiolate catalytic activation of inert Caryl-hetero bonds for radical borylation

K?nig, Burkhard,Wang, Hua,Wang, Shun

supporting information, p. 1653 - 1665 (2021/06/17)

Substantial effort is currently being devoted to obtaining photoredox catalysts with high redox power. Yet, it remains challenging to apply the currently established methods to the activation of bonds with high bond dissociation energy and to substrates with high reduction potentials. Herein, we introduce a novel photocatalytic strategy for the activation of inert substituted arenes for aryl borylation by using thiolate as a catalyst. This catalytic system exhibits strong reducing ability and engages non-activated Caryl–F, Caryl–X, Caryl–O, Caryl–N, and Caryl–S bonds in productive radical borylation reactions, thus expanding the available aryl radical precursor scope. Despite its high reducing power, the method has a broad substrate scope and good functional-group tolerance. Spectroscopic investigations and control experiments suggest the formation of a charge-transfer complex as the key step to activate the substrates.

Synthesis method of fluorine-containing phenol structure compound

-

Paragraph 0025-0026, (2021/03/13)

The invention discloses a synthesis method of a fluorine-containing phenol structure compound, and belongs to the technical field of chemical synthesis. Fluorine-containing benzoic acid is subjected to a one-pot reaction in a solvent under the action of alkali to obtain fluorine-containing phenate, and fluorine-containing phenol is obtained after acid regulation and dissociation. The synthesis method has the advantages of rich, cheap and easily available raw material structure, short synthesis steps, mild reaction conditions, simple and convenient operation, high synthesis yield, good productquality, wide application range and the like, and is suitable for simple and efficient synthesis of various high-value and high-purity fluorine-containing phenol compounds.

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