129064-19-3Relevant academic research and scientific papers
Stereoselective Synthesis of Alcohols, XXXVI Stereoselective Generation of Homoallyl Alcohols Having Quarternary Stereogenic Centers
Hoffmann, Reinhard W.,Schlapbach, Achim
, p. 1243 - 1248 (2007/10/02)
E- and Z-γ,γ-disubstituted allylboronates 12 have been generated by the carbocupration of alkynes and subsequent homologation.These allylboronates add to aldehydes, forming the homoallyl alcohols 13 and 14 with 88-99percent simple diastereoselectivity.The
