129098-11-9Relevant academic research and scientific papers
Nonenzymatic enantioselective acylation of racemic secondary alcohols catalyzed by a SnX2-Chiral diamine complex
Oriyama, Takeshi,Hori, Yoko,Imai, Keisuke,Sasaki, Ryosuke
, p. 8543 - 8546 (1996)
Kinetic resolution of racemic secondary alcohols has been achieved by the reaction with benzoyl halide in the presence of a SnX2-chiral diamine complex to afford the corresponding benzoate in good to excellent enantioselectivities.
(S)-proline-derived catalysts for the acylative kinetic resolution of alcohols: A remote structural change allows a complete selectivity switch
Gleeson, Oliver,Gun'Ko, Yurii K.,Connon, Stephen J.
supporting information, p. 1728 - 1734 (2013/09/02)
A systematic preliminary study has identified a suite of catalysts, all readily prepared and derived from (S)-proline, which differ by a remote substituent only. If this substituent is capable of hydrogen-bond donation the catalyst will promote the resolu
Novel, Enantioselective Lactone Construction. First Synthesis of Methylenolactocin, Antitumor Antibiotic from Penicillium sp.
Azevedo, Mariangela B. M. de,Murta, Maria M.,Greene, Andrew E.
, p. 4567 - 4569 (2007/10/02)
The first synthesis of (-)-methylenolactocin, which illustrates a novel approach to enantiopure γ-butyrolactones and serves to confirm the structure and establish the absolute stereochemistry of the natural product, is reported.
