Nonenzymatic enantioselective acylation of racemic secondary alcohols catalyzed by a SnX2-Chiral diamine complex

DOI: 10.1016/0040-4039(96)01987-9

Source and publish data:

Tetrahedron Letters p. 8543 - 8546 (1996)

Update date:2022-08-11

Topics:

Authors:

Oriyama, Takeshi

Hori, Yoko

Imai, Keisuke

Sasaki, Ryosuke

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Article abstract of DOI:10.1016/0040-4039(96)01987-9

Kinetic resolution of racemic secondary alcohols has been achieved by the reaction with benzoyl halide in the presence of a SnX₂-chiral diamine complex to afford the corresponding benzoate in good to excellent enantioselectivities.

Full text of DOI:10.1016/0040-4039(96)01987-9

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