129141-44-2

Upstream product

• 10467-10-4 ethylmagnesium iodide 
• 94482-90-3 (S)-2-(2',2'-Dimethyl-1',3'-dioxolan-4'-yl)-2-oxoethylbenzoate 
• 91274-05-4 (2S,3S)-1,2-O-isopropylidene-1,2,3,4-tetrol 
• 92973-40-5 methyl (2R,3S)-3,4-O-isopropylidene-2,3,4-trihydroxybutanoate 
• 98-88-4 benzoyl chloride 
• 94451-17-9 (2S,4'S)-2-(2',2'-Dimethyl-1',3'-dioxolan-4'-yl)-2-hydroxyethyl benzoate 
• 925-90-6 ethylmagnesium bromide 

Relevant academic research and scientific papers

Diastereoselective Addition of Grignard Reagents to 3,4-O-Isopropylidene-1-O-triphenylmethyl-L-glycero-2-tetrulose and 1-O-Benzoyl-3,4-O-isopropylidene-L-glycero-2-tetrulose

Diastereoselectivity in the addition of Grignard reagents (RMgX) to 3,4-O-isopropylidene-1-O-triphenylmethyl-L-glycero-2-tetrulose (1) and 1-O-benzoyl-3,4-O-isopropylidene-L-glycero-2-tetrulose (2) depended remarkably on R, X, the solvent, and the reactio

Diastereoselective Addition of Organometallics to 3,4-O-Isopropylidene-l-glycero-2-tetrulose Derivatives

Diastereoselectivity in the addition of Grignard reagents (RMgX) to 1-O-benzoyl-3,4-O-isopropylidene-L-glycero-2-tetrulose and 3,4-isopropylidene-1-O-triphenylmethyl-L-glycero-2-tetrulose (2) depended remarkably on X, R, and the reaction temperature.The addition of EtMgBr, i-PrMgBr, and BuMgCl to 2 at 0 deg C gave (2R,3S)-adducts with high diastereoselectivity ( 94percent de).