94482-90-3

Upstream product

• 94451-17-9 (2S,4'S)-2-(2',2'-Dimethyl-1',3'-dioxolan-4'-yl)-2-hydroxyethyl benzoate 
• 92973-40-5 methyl (2R,3S)-3,4-O-isopropylidene-2,3,4-trihydroxybutanoate 
• 98-88-4 benzoyl chloride 
• 91274-05-4 (2S,3S)-1,2-O-isopropylidene-1,2,3,4-tetrol 
• 94451-15-7 4-O-benzoyl-2-O-benzyl-1,2-O-isopropylidene-L-threitol 
• 84379-53-3 2-O-benzyl-3,4-O-isopropylidene-L-threitol 

Downstream Products

• 129141-44-2 (2S,3S)-1-O-benzoyl-2-ethyl-3,4-O-isopropylidene-1,2,3,4-butanetetrol 
• 129141-44-2 (2R,3S)-1-O-benzoyl-2-ethyl-3,4-O-isopropylidene-1,2,3,4-butanetetrol 
• 107701-33-7 (R)-2-(2',2'-Dimethyl-1',3'-dioxolan-4'-yl)-6,10-dimethyl-2,5,9-undecatrien-1-yl benzoate 
• 145242-11-1 Toluene-4-sulfonic acid (R)-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-hexadecyl ester 
• 145242-10-0 Toluene-4-sulfonic acid (S)-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-undecyl ester 
• 107701-31-5 (R)-2-(1'-Hydroxy-2'-tosyloxyethyl)-6,10-dimethyl-2,5,9-undecatrien-1-yl benzoate 
• 107710-95-2 (R)-2-(1',2'-Dihydroxyethyl)-6,10-dimethyl-2,5,9-undecatrien-1-yl benzoate 
• 107701-32-6 (R)-2-(1'-Hydroxy-2'-bromoethyl)-6,10-dimethyl-2,5,9-undecatrien-1-yl benzoate 
• 129141-43-1 (2R,3S)-1-O-benzoyl-3,4-O-isopropylidene-2-methyl-1,2,3,4-butanetetrol 
• 129141-42-0 (2S,3S)-1-O-benzoyl-3,4-O-isopropylidene-2-methyl-1,2,3,4-butanetetrol 
• 129141-48-6 (2R,3S)-3,4-O-isopropylidene-2-methyl-1,2,3,4-butanetetrol 
• 129141-47-5 (2S,3S)-3,4-O-isopropylidene-2-methyl-1,2,3,4-butanetetrol 

Relevant academic research and scientific papers

Diastereoselective Addition of Grignard Reagents to 3,4-O-Isopropylidene-1-O-triphenylmethyl-L-glycero-2-tetrulose and 1-O-Benzoyl-3,4-O-isopropylidene-L-glycero-2-tetrulose

Diastereoselectivity in the addition of Grignard reagents (RMgX) to 3,4-O-isopropylidene-1-O-triphenylmethyl-L-glycero-2-tetrulose (1) and 1-O-benzoyl-3,4-O-isopropylidene-L-glycero-2-tetrulose (2) depended remarkably on R, X, the solvent, and the reactio

Diastereoselective Addition of Organometallics to 3,4-O-Isopropylidene-l-glycero-2-tetrulose Derivatives

Diastereoselectivity in the addition of Grignard reagents (RMgX) to 1-O-benzoyl-3,4-O-isopropylidene-L-glycero-2-tetrulose and 3,4-isopropylidene-1-O-triphenylmethyl-L-glycero-2-tetrulose (2) depended remarkably on X, R, and the reaction temperature.The addition of EtMgBr, i-PrMgBr, and BuMgCl to 2 at 0 deg C gave (2R,3S)-adducts with high diastereoselectivity ( 94percent de).