129144-54-3Relevant academic research and scientific papers
Novel ruthenium-catalyzed synthesis of 1,3-dioxolan-4-ones from α-hydroxy acids and terminal alkynes via enol esters
Neveux, Muriel,Seiller, Benedicte,Hagedorn, Frauke,Bruneau, Christian,Dixneuf, Pierre H.
, p. 133 - 138 (2007/10/02)
α-Hydroxy acids react with terminal alkynes, in the presence of binuclear ruthenium complexes 2 as catalyst precursors, to selectively afford either α-hydroxy enol esters or their cyclization products 1,3-dioxolan-4-ones.
Chirality transfer from lactic acid selective synthesis of 2,2-disubstituted-1,3-dioxolan-4-ones from ketones and acetals
Greiner,Ortholand
, p. 2135 - 2138 (2007/10/02)
Diastereomeric 2,2-disubstituted-5-methyl-1,3-dioxolan-4-ones were prepared from lactic acid and ketones or their acetals with excellent control of stereochemistry under kinetic or thermodynamic reaction conditions.
