129152-22-3

Upstream product

• 186581-53-3 diazomethane 
• 504-02-9 1,3-cylohexanedione 
• 926-57-8 1,3-dichloro-2-butene 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 55444-67-2 trimethyl ortho-4-bromobutanoate 
• 73336-23-9 4-(3-oxo-cyclohex-1-enyl)-butyric acid 
• 78877-14-2 3-(4-hydroxybutyl)-2-cyclohexen-1-one 

Downstream Products

• 129152-23-4 4-(3-Hydroxy-cyclohex-1-enyl)-butyric acid methyl ester 
• 284464-11-5 3-(4-hydroxy-4-methyl-pentyl)-1-methyl-cyclohex-2-enol 
• 129152-28-9 4-(1-Hydroxy-cyclohex-2-enyl)-butyric acid methyl ester 
• 284036-46-0 3-(4-hydroxy-4-methyl-pentyl)-cyclohex-2-enol 

Relevant academic research and scientific papers

Amberlyst-15-catalyzed intramolecular S(N)2' oxaspirocyclization of secondary allylic alcohols. Application to the total synthesis of spirocyclic ethers theaspirane and theaspirone

A variety of substituted 1-oxaspiro[4.4]non-6-ene. 1-oxaspiro[4.5]dec-6- ene, 6-oxaspiro[4.5]dec-1-ene and 1-oxaspiro[5.5]undec-7-ene systems have been prepared by utilizing Amberlyst-15-catalyzed intramolecular S(N)2' oxaspirocyclizations of secondary allylic alcohols under mild reaction conditions in quantitative yields. This oxaspirocyclization was applied to the total synthesis of theaspirane and theaspirone from β-ionone in five steps. (C) 2000 Elsevier Science Ltd.

Amberlyst-15-catalyzed intramolecular S(N)2' oxaspirocyclization of tertiary allylic alcohols

A variety of substituted 1-oxaspiro[4.5]dec-6-ene and 1- oxaspiro[5.5]undec-7-ene systems have been prepared by utilizing Amberlyst- 15-catalyzed S(N)2' oxaspirocyclizations under mild reaction conditions (- 20°C) in quantitative yields. In this process,

Synthesis of Carbocyclic Systems via Radical-Induced Epoxide Fragmentation

Cis-fused bicyclic compounds are synthesized from simple monocyclic enone precursors.The key step involves a tandem radical-mediated epoxide fragmentation, radical translocation, and cyclization.