129178-79-6

Basic information

• Product Name: 3-Phenyl-2-(phenylseleno)-3-(trimethylsilyl)-1-propanol
• CAS NO: 129178-79-6
• Molecular Weight: 363.433
• Mol File: 129178-79-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Phenyl-2-(phenylseleno)-3-(trimethylsilyl)-1-propanol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Phenyl-2-(phenylseleno)-3-(trimethylsilyl)-1-propanol(129178-79-6)
• EPA Substance Registry System: 3-Phenyl-2-(phenylseleno)-3-(trimethylsilyl)-1-propanol(129178-79-6)

Safety Data

• Hazardous Substances Data: 129178-79-6(Hazardous Substances Data)

Upstream product

• 129178-75-2 (Z)-3-Phenyl-1-(trimethylsilyloxy)-3-(trimethylsilyl)-1-propene 
• 30263-03-7 3-Phenyl-3-(trimethylsilyl)-1-propanol 
• 30262-97-6 3-Phenyl-3-(trimethylsilyl)propanal 
• 129178-71-8 3-Phenyl-2-(phenylseleno)-3-(trimethylsilyl)propanal 
• 94286-29-0 methyl (RS)-3-phenyl-3-trimethylsilylpropanoate 

Downstream Products

• 35802-50-7 3-phenyl-3-(trimethylsilyl)prop-1-ene 
• 69562-10-3 1-phenyl-3-phenylseleno-1-propene 

Relevant articles and documents

REGIO- AND STEREOSELECTIVE SYNTHESIS OF ALLYLTRIMETHYLSILANES VIA KRIEF-REICH ELIMINATION IN β-SELENO-γ-SILYL ALCOHOLS

The synthesis of (E)-allyltrimethylsilanes by regio- and stereocontrolled pathways is described based on the preference for Krief-Reich elimination over silicon-controlled rearrangement in β-seleno-γ-silyl alcohols, readily available from α-selenoaldehydes, 10 - 12.Usefulness of this protocol for the introduction of the allylsilane function α to the carbonyl group in cycloalkanones as well as for the preparation of unsymmetrically substituted allylsilanes is also reported.