129194-38-3Relevant academic research and scientific papers
A carboxylate-assisted amination/unactivated C(sp2)-H arylation reactionviaa palladium/norbornene cooperative catalysis
An, Yang,Zhang, Bo-Sheng,Zhang, Zhe,Liu, Ce,Gou, Xue-Ya,Ding, Ya-Nan,Liang, Yong-Min
supporting information, p. 5933 - 5936 (2020/06/04)
This report describes a carboxylate-assisted palladium-catalysed Catellani reaction, which is compatible withortho-amination and unactivated C(sp2)-H arylation. This method was used to synthesize a series of 1-amino substituted dihydrophenanthridines, phenanthridines and 6H-benzo[c]chromenes. Based on kinetic isotope experiments, the kinetic curve proves that pivalic acid accelerates the reaction rate of unactivated C(sp2)-H activation, and thus this rate can keep up with the five membered aryl-norbornene-palladacycle (ANP) intermediate.
Polar Effects in the Decomposition of Bis(3-alkoxyaroyl) Peroxides. Synthesis of 8-Alkoxy-6H-dibenzopyran-6-ones
Auricchio, Sergio,Citterio, Attilio,Sebastiano, Roberto
, p. 6312 - 6316 (2007/10/02)
The reaction of four substituted bis(3-alkoxybenzoyl) peroxides (1b-e) in neat phenols (2a-e) affords mainly 8-alkoxy-6H-dibenzopyran-6-ones (7) and ortho-benzoyloxylation products (4) of the phenol.Diaroyl peroxides without electron-releasing meta substituents afford essentially products 4.A mechanism involving monoelectronic oxidation of the phenol by the peroxide and biaryl coupling by preferential addition of the phenol radical cation to the ortho positions to the alkoxy group of the diaroyl peroxide is suggested.
