129217-19-2

Upstream product

• 129217-18-1 (2-oxooxazolidin-4-yl)(phenyl)methyl benzoate 
• 127870-54-6 Benzoic acid (4S,5R)-2-oxo-5-phenyl-oxazolidin-4-ylmethyl ester 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 129217-45-4 Benzoyl-carbamic acid 1-phenyl-allyl ester 
• 129217-44-3 Cinnamyl Benzoylcarbamate 
• 129217-17-0 3-phenyl-2(R*),3(R*)-epoxypropyl benzoylcarbamate 
• 127870-52-4 2(R*),3-epoxy-1(R*)-phenylpropyl benzoylcarbamate 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 1375105-52-4 C₁₈H₂₈O₃Si 
• 1375105-48-8 C₁₇H₂₆O₄Si 
• 3313-19-7 (1RS,2SR)-2-acetylamino-1-phenyl-propane-1,3-diol 
• 164853-29-6 (±)-methyl 2-{[(tert-butyldimethylsilyl)oxy](phenyl)methyl}prop-2-enoate 
• 868659-35-2 (+/-)-2-[(tert-butyldimethylsilyloxy)(phenyl)methyl]-2-prop-2-en-1-ol 
• 1424055-61-7 (Z)-3-phenylallyl benzoyloxycarbamate 

Relevant academic research and scientific papers

Iron(II)-catalyzed intramolecular aminohydroxylation of olefins with functionalized hydroxylamines

A diastereoselective aminohydroxylation of olefins with a functionalized hydroxylamine is catalyzed by new iron(II) complexes. This efficient intramolecular process readily affords synthetically useful amino alcohols with excellent selectivity (dr up to > 20:1). Asymmetric catalysis with chiral iron(II) complexes and preliminary mechanistic studies reveal an iron nitrenoid is a possible intermediate that can undergo either aminohydroxylation or aziridination, and the selectivity can be controlled by careful selection of counteranion/ligand combinations.

Diastereoselective synthesis of substituted 2-Amino-1,3-propanediols from morita Baylis-Hillman adducts

We report herein a new diastereoselective approach to substituted 2-amino-1,3-propanediols with anti relative stereochemistry from Morita-Baylis-Hillman (MBH) adducts. These structural moieties have been used as intermediates for the synthesis of several

N-BENZOYLCARBAMATE CYCLIZATIONS

The anion of an alcohol derived N-benzoylcarbamate may be used to deliver nitrogen intramolecularly to electrophilic centers.This allows the stereocontrolled synthesis of a variety of amino-alcohol and amino-diol derivatives.