868659-35-2Relevant academic research and scientific papers
Diastereoselective synthesis of substituted 2-Amino-1,3-propanediols from morita Baylis-Hillman adducts
Paioti, Paulo H. S.,Rezende, Patri?cia,Coelho, Fernando
experimental part, p. 285 - 293 (2012/05/05)
We report herein a new diastereoselective approach to substituted 2-amino-1,3-propanediols with anti relative stereochemistry from Morita-Baylis-Hillman (MBH) adducts. These structural moieties have been used as intermediates for the synthesis of several
Stereoselective and diversity-oriented synthesis of trisubstituted allylic alcohols and amines
Schmidt, Yvonne,Breit, Bernhard
, p. 11789 - 11796 (2011/11/06)
Stereoselective and diversity-oriented synthesis of trisubstituted olefins was achieved by using ortho-diphenylphosphanyl benzoate (o-DPPB) as a directing group for allylic substitution. The starting point of this methodology was a set of α-methylene alde
Diastereoselective epoxidation of allylic diols derived from Baylis-Hillman adducts
Porto, Ricardo S.,Vasconcellos, Mario L. A. A.,Ventura, Elizete,Coelho, Fernando
, p. 2297 - 2306 (2007/10/03)
The results of a highly diastereoselective epoxidation of allylic diols derived from Baylis-Hillman adducts are reported. The formation of an intramolecular hydrogen bond seems to be responsible for the high anti diastereoselection obtained in this epoxid
1,4-asymmetric induction in the chromium(II)- and indium-mediated coupling of allyl bromides to aldehydes
Maguire, Robert J.,Mulzer, Johann,Bats, Jan W.
, p. 6936 - 6940 (2007/10/03)
A series of allyl bromides bearing an ethereal stereogenic substituent at C-2 were synthesized from methyl acrylate. These were coupled with a range of aldehydes under chromium(II) chloride-mediated conditions to afford syn-4-alkoxyalkan-1-ols in good yie
