129222-20-4Relevant academic research and scientific papers
Studies of the solid-phase Pauson-Khand reaction: Selective in-situ enone reduction to 3-azabicyclo[3.3.0] octanones
Becker, Daniel P.,Flynn, Daniel L.
, p. 2087 - 2090 (1993)
The Smit-Caple DSAC Pauson-Khand cyclization of a series of N-protected allyl propargyl amines in the absence of oxygen gave rise to formation of the saturated azabicyclo[3.3.0]octanones in excellent yields. Standard cyclization in air gave mixtures of sa
The Synthesis of Nitrogen Heterocycles via the Intramolecular Khand Reaction: Formation of Tetra- and Hexa-hydrocyclopentapyrrol-5(1H)-ones and Hexahydro-6H-2-pyrindin-6-ones
Brown, Scott W.,Pauson, Peter L.
, p. 1205 - 1209 (2007/10/02)
Azabicyclooctenones and azabicyclononenones have been obtained by cyclisation of hexacarbonyldicobalt complexes of aza-heptenynes and -octenynes respectively.An unusual feature of the cyclisation of N-acyl-4-azahept-1-en-6-ynes is the extens
