129222-57-7Relevant articles and documents
DENTAL MATERIALS WITH DEBONDING-ON-DEMAND PROPERTIES
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Paragraph 0118; 0119; 0120, (2017/08/01)
Radically polymerizable dental material, which contains at least one compound of Formula I: and at least one thermolabile radically polymerizable compound and/or at least one photolabile radically polymerizable compound. The materials are characterized by
Free radical addition reactions of allylic sulfones to alkenes
Harvey, Iain W.,Phillips, Eifion D.,Whitham, Gordon H.
, p. 6493 - 6508 (2007/10/03)
Intermolecular radical reactions involving formal addition of the sulfonyl and allyl fragments of an allylic sulfone across the double bond of an alkene are described. Reactions are most successful when the allylic sulfone has an electron withdrawing group at the 2-position. Only monosubstituted alkenes give useful yields of adducts, though both electron withdrawing and electron donating substituents are effective.