129222-57-7

Basic information

• Product Name: 2-{[(4-methylphenyl)sulfonyl]methyl}acrylonitrile
• Synonyms: 2-{[(4-methylphenyl)sulfonyl]methyl}acrylonitrile
• CAS NO: 129222-57-7
• Molecular Formula: C₁₁H₁₁NO₂S
• Molecular Weight: 221.27554
• Mol File: 129222-57-7.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-{[(4-methylphenyl)sulfonyl]methyl}acrylonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 2-{[(4-methylphenyl)sulfonyl]methyl}acrylonitrile(129222-57-7)
• EPA Substance Registry System: 2-{[(4-methylphenyl)sulfonyl]methyl}acrylonitrile(129222-57-7)

Safety Data

• Hazardous Substances Data: 129222-57-7(Hazardous Substances Data)

Upstream product

• 1950-78-3 p-toluenesulfonyl iodide 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 126-98-7 methacrylonitrile 

Downstream Products

• 129222-60-2 4-acetoxy-2-methylene-5-(4-methylphenylsulfonyl)pentanonitrile 

Relevant articles and documents

DENTAL MATERIALS WITH DEBONDING-ON-DEMAND PROPERTIES

Radically polymerizable dental material, which contains at least one compound of Formula I: and at least one thermolabile radically polymerizable compound and/or at least one photolabile radically polymerizable compound. The materials are characterized by

Free radical addition reactions of allylic sulfones to alkenes

Intermolecular radical reactions involving formal addition of the sulfonyl and allyl fragments of an allylic sulfone across the double bond of an alkene are described. Reactions are most successful when the allylic sulfone has an electron withdrawing group at the 2-position. Only monosubstituted alkenes give useful yields of adducts, though both electron withdrawing and electron donating substituents are effective.