1292358-76-9Relevant academic research and scientific papers
Rhodium-Catalyzed Denitrogenative Transannulation of N-Sulfonyl-1,2,3-triazoles with Glycals Giving Pyrroline-Fused N-Glycosides
Bi, Jingjing,Tan, Qiang,Wu, Hao,Liu, Qingfeng,Zhang, Guisheng
supporting information, p. 6357 - 6361 (2021/08/23)
Described here is a selective synthesis of 2,3-dihydropyrrole-fused N-glycosides through rhodium-catalyzed denitrogenative transannulation of N-sulfonyl-1,2,3-triazoles with glycals. A series of pyrroline-fused N-glycosides are afforded in moderate to exc
METHOD OF PRODUCING SULFONYL OR SULFAMOYL TRIAZOLE-BASED COMPOUNDS USING CONTINUOUS FLOW PROCESS
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Paragraph 0159-0163, (2019/12/25)
The present invention relates to a method for manufacturing a sulfonyl or sulfamoyl triazole-based compound using a continuous flow process. According to embodiments of the present specification, the sulfonyl or sulfamoyl triazole-based compound frequentl
Cu2O acting as a robust catalyst in CuAAC reactions: Water is the required medium
Wang, Kai,Bi, Xihe,Xing, Shuangxi,Liao, Peiqiu,Fang, Zhongxue,Meng, Xianyu,Zhang, Qian,Liu, Qun,Ji, Yu
supporting information; experimental part, p. 562 - 565 (2011/05/03)
Cu2O as the catalyst in water was found to be quite robust for the azide-alkyne cycloaddition (AAC) reaction, which was verified by a wide variety of applicable azides and alkynes. Water was proved to play an essential role because of a significant rate acceleration compared with reactions using organic solvents and conducted under neat conditions. The high catalytic performance of Cu2O/H2O system was further argued by decreasing the catalyst loading to ppm levels. The Royal Society of Chemistry.
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes
Chuprakov, Stepan,Malik, Jamal A.,Zibinsky, Mikhail,Fokin, Valery V.
supporting information; experimental part, p. 10352 - 10355 (2011/08/05)
A highly efficient enantioselective C-H insertion of azavinyl carbenes into unactivated alkanes has been developed. These transition metal carbenes are directly generated from readily available and stable 1-sulfonyl-1,2,3-triazoles in the presence of chiral Rh(II) carboxylates and are used for C-H functionalization of alkanes to access a variety of β-chiral sulfonamides.
