1293-67-0 Usage
Uses
Used in Organic and Inorganic Synthesis:
Ferrocene,1,1'-dichlorois utilized as a catalyst or precursor in the synthesis of various organic and inorganic compounds. Its presence facilitates numerous chemical reactions, enhancing the efficiency and selectivity of the synthesis processes.
Used in Pharmaceutical Production:
In the pharmaceutical industry, Ferrocene,1,1'-dichlorois employed as a key intermediate in the production of certain drugs. Its unique chemical properties allow for the development of novel therapeutic agents with improved efficacy and reduced side effects.
Used in Dye Manufacturing:
Ferrocene,1,1'-dichlorois used as a starting material in the synthesis of various dyes. The incorporation of the ferrocene core and chlorine atoms imparts distinctive color characteristics and stability to the resulting dyes, making them suitable for a wide range of applications, including textiles, plastics, and printing inks.
Used in Polymer Synthesis:
In the polymer industry, Ferrocene,1,1'-dichlorois employed as a monomer or a modifying agent in the synthesis of polymers with specific properties. The introduction of the ferrocene unit can impart unique characteristics, such as conductivity or magnetic properties, to the resulting polymers, broadening their potential applications.
Used in Materials Science Research:
Ferrocene,1,1'-dichlorois extensively used in research and development activities within the field of materials science. Its unique structure and properties make it an ideal candidate for the exploration of new materials with novel functionalities, such as conductive materials, magnetic materials, and catalysts for various chemical reactions.
Used in Chemical Engineering:
In chemical engineering, Ferrocene,1,1'-dichlorois employed as a catalyst or a precursor in various chemical processes. Its presence can improve the efficiency, selectivity, and yield of these processes, contributing to the advancement of chemical engineering technologies and the development of new industrial applications.
Check Digit Verification of cas no
The CAS Registry Mumber 1293-67-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,2,9 and 3 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1293-67:
(6*1)+(5*2)+(4*9)+(3*3)+(2*6)+(1*7)=80
80 % 10 = 0
So 1293-67-0 is a valid CAS Registry Number.
1293-67-0Relevant academic research and scientific papers
Acceptor-substituted ferrocenium salts as strong, single-electron oxidants: Synthesis, electrochemistry, theoretical investigations, and initial synthetic application
Khobragade, Dushant A.,Mahamulkar, Shraddha G.,Pospí?il, Lubomír,Císa?ová, Ivana,Rulí?ek, Lubomír,Jahn, Ullrich
supporting information, p. 12267 - 12277 (2012/11/14)
A series of mono- and 1,1'-diheteroatom-substituted ferrocene derivatives as well as acylated ferrocenes was prepared efficiently by a unified strategy that consists of selective mono- and 1,1'-dilithiation reactions and subsequent coupling with carbon, phosphorus, sulfur and halogen electrophiles. Chemical oxidation of the ferrocene derivatives by benzoquinone, 2,3-dichloro-5,6- dicyanobenzoquinone, AgPF6, or 2,2,6,6-tetramethyl-1-oxopiperidinium hexafluorophosphate provided the corresponding ferrocenium salts. The redox potentials of the synthesized ferrocenes were determined by cyclic voltammetry, and it was observed that all new ferrocenium salts have stronger oxidizing properties than standard ferrocenium hexafluorophosphate. An initial application of selected derivatives in an oxidative bicyclization revealed that they mediate the transformation under considerably milder conditions than ferrocenium hexafluorophosphate. Quantum chemical calculations of the reduction potentials of the substituted ferrocenium ions were carried out by using a standard thermodynamic cycle that involved the gas-phase energetics and solvation energies of the contributing species. A remarkable agreement between theory and experiment was found: the mean average deviation amounted to only 0.030-V and the maximum deviation to 0.1-V. This enabled the analysis of various physical contributions to the computed reduction potentials of these ferrocene derivatives, thereby providing insight into their electronic structure and physicochemical properties. Copyright
Ferrocene Derivatives. Part 22. Friedel-Crafts Arylations with Chloroferrocenes. A New Route to Arylferrocenes.
Pauson, Peter L.,Sraga, Jan,Toma, Stefan
, p. 1233 - 1236 (2007/10/02)
In the presence of anhydrous aluminium chloride and aluminium, chloro- and 1,1'-dichloro-ferrocenes act as moderately efficient reagents for the Friedel-Crafts arylation (i.e. 'ferrocenylation') of simple arenes.Extensive reductive dechlorination also occurs.
