1293324-03-4

Basic information

• Product Name: tert-butyl (2-bromo-4-methylbenzyl)carbamate
• Synonyms: tert-butyl (2-bromo-4-methylbenzyl)carbamate
• CAS NO: 1293324-03-4
• Molecular Weight: 300.195
• Mol File: 1293324-03-4.mol

Chemical Properties

• CAS DataBase Reference: tert-butyl (2-bromo-4-methylbenzyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl (2-bromo-4-methylbenzyl)carbamate(1293324-03-4)
• EPA Substance Registry System: tert-butyl (2-bromo-4-methylbenzyl)carbamate(1293324-03-4)

Safety Data

• Hazardous Substances Data: 1293324-03-4(Hazardous Substances Data)

Upstream product

• 824-54-4 2-bromo-4-methylbenzaldehyde 
• 865718-75-8 1-(2-bromo-4-methylphenyl)methanamine 
• 24424-99-5 di-tert-butyl dicarbonate 

Downstream Products

• 1410130-09-4 C₂₃H₃₀N₂O₄S 
• 1410130-06-1 C₂₅H₃₄N₂O₆S 
• 1410130-03-8 C₂₅H₄₂N₂O₄S 
• 1410129-98-4 C₂₂H₂₇ClN₂O₄S 
• 1410130-01-6 C₂₁H₃₂N₂O₄S 
• 1410131-22-4 3-(4-chlorobenzyl)-9-methyl-3,4,6,10b-tetrahydro-1H-[1,2,4]thiadiazino[5,4-a]isoindole 2,2-dioxide 
• 1410131-16-6 3-cyclohexyl-9-methyl-3,4,6,10b-tetrahydro-1H-[1,2,4]thiadiazino[5,4-a]isoindole 2,2-dioxide 
• 1410131-10-0 3-(3,4-dimethoxyphenylethyl)-9-methyl-3,4,6,10b-tetrahydro-1H-[1,2,4]thiadiazino[5,4-a]isoindole 2,2-dioxide 
• 1410131-23-5 9-methyl-3-(1-phenylethyl)-6,10b-dihydro-1H-[1,2,4]thiadiazino[5,4-a]isoindol-4(3H)-one 2,2-dioxide 
• 1410131-17-7 3-(4-chlorobenzyl)-9-methyl-6,10b-dihydro-1H-[1,2,4]thiadiazino[5,4-a]isoindol-4(3H)-one 2,2-dioxide 
• 1410131-13-3 3-cyclohexyl-9-methyl-6,10b-dihydro-1H-[1,2,4]thiadiazino[5,4-a]isoindol-4(3H)-one 2,2-dioxide 
• 1410131-09-7 3-(3,4-dimethoxyphenylethyl)-9-methyl-6,10b-dihydro-1H-[1,2,4]thiadiazino[5,4-a]isoindol-4(3H)-one 2,2-dioxide 
• 1358685-34-3 C₁₉H₃₀N₂O₄S 
• 1358685-38-7 C₂₃H₃₈N₂O₄S 

Relevant articles and documents

Asymmetric Hydrogenation of Dibenzo[ c,e]azepine Derivatives with Chiral Cationic Ruthenium Diamine Catalysts

An efficient Ru-catalyzed asymmetric hydrogenation of dibenzo[c,e]azepines is reported. A series of seven-membered cyclic amines were obtained with moderate to excellent enantioselectivity. The catalyst counteranion played an important role in achieving high-level chiral induction. Moreover, a one-pot synthesis of chiral 6,7-dihydro-5H-dibenz[c,e]azepines via two-step reductive amination was also developed.

Palladium-Catalyzed α-Arylation of Silylenol Ethers in the Synthesis of Isoquinolines and Phenanthridines

A diverse array of isoquinolines and phenanthridines have been accessed by developing a two-step, one-pot method constituting regioselective palladium-catalyzed Kuwajima-Urabe α-arylation of silylenol ethers and acid-mediated deprotection, annulation, and aromatization. Structural diversity in the silylenol ethers leads to three different classes of isoquinolines and phenanthridines from which related natural products can be derived. The synthetic utility of this method by the quick assembly of the natural product trispheridine is also demonstrated.