129512-44-3Relevant academic research and scientific papers
Tert-Butyldimethylsilyl Amine (TBDMS-NH2): A Mild and Green Reagent for the Protection of Benzyl Alcohols, Phenols, and Carboxylic Acids under Solvent-Free Conditions
Duczynski, Jeremy A.,Fuller, Rebecca,Stewart, Scott G.
, p. 1172 - 1179 (2016/10/13)
Herein, we present the use of the tert-butyldimethylsilyl amine (TBDMS-NH2) as a silylating reagent for phenols, benzyl alcohols, and carboxylic acids. Unlike other silyl protection reactions, this reported process with TBDMS-NH2 does not involve the form
A Novel Synthesis of 4H-Chromen-4-ones via Intramolecular Wittig Reaction
Kumar, Pradeep,Bodas, Mandar S.
, p. 3821 - 3823 (2007/10/03)
formula presented The acylphosphoranes formed in a sequential manner from the reaction of the silyl ester of O-acyl(aroyl)salicylic acids and (trimethylsilyl)-methylenetriphenylphosphorane undergo intramolecular Wittig cyclization on the ester carbonyl to afford the 4H-chromen-4-ones in good to excellent yields.
Photooxygenation of 3- and 2-silyloxybenzofurans: Rearrangement of dioxetanes via α-silylperoxy ketones to ketoester cleavage products
Adam,Kades,Wang
, p. 2259 - 2262 (2007/10/02)
Photooxygenation of 2-methyl-3-silyloxybenzofurans 1 afforded isolable dioxetranes 2, the latter rearranged via α-silylperoxy ketones 3 to cleavage products 4; 2-silyloxy-3-methylbenzofuran 6 with 1O2 gave the more stable dioxetane 7.
