129571-71-7Relevant articles and documents
Counteranion-controlled regioselectivity in palladium-catalyzed allylic amination of dienyl allylic carbonates
Shen, Meng-Lan,Wang, Pu-Sheng,Gong, Liu-Zhu
supporting information, (2021/03/01)
A regioselective Pd-catalyzed allylic amination reaction of dienyl allylic carbonates and aromatic amines has been developed by means of phosphoramidite-palladium catalysis. The regioselectivity could be altered by the counterion of the π-allylpalladium intermediate. As a result, either branched Z-dienyl allylic amines or linear conjugated allylic amines were generated in high levels of regioselectivity from the same substrates by tuning the reaction conditions.
Iridium-Catalyzed Asymmetric Allylic Alkylation of Deconjugated Butyrolactams
Mitra, Sankash,Mukherjee, Santanu
supporting information, p. 3021 - 3026 (2021/05/04)
Compared with the ever-growing list of nonprochiral nucleophiles in Ir-catalyzed asymmetric allylic substitution reactions, prochiral nucleophiles are less studied. We present a new prochiral nucleophile, namely, deconjugated butyrolactam, for Ir-catalyze
Chiral naphthyl-C2-indole as scaffold for phosphine organocatalysis: Application in asymmetric formal [4 + 2] cycloaddition reactions
He, Tingting,Peng, Lei,Li, Shan,Hu, Fangli,Xie, Chuandong,Huang, Shengli,Jia, Shiqi,Qin, Wenling,Yan, Hailong
supporting information, p. 6966 - 6971 (2020/09/15)
The applications of a newly designed chiral naphthyl-C2-indole bifunctional phosphine organocatalyst in stereoselective formal [4 + 2] cycloaddition reactions were reported. The chiral naphthyl-C2-indole skeleton was introduced to bifunctional phosphine o