129646-78-2Relevant articles and documents
Chemoenzymatic dynamic kinetic resolution of allylic alcohols: A highly enantioselective route to acyloin acetates
Bogar, Krisztian,Vidal, Pilar Hoyos,Alcantara Leon, Andres R.,Baeckvall, Jan-E.
, p. 3401 - 3404 (2007)
Dynamic kinetic resolution (DKR) of a series of sterically hindered allylic alcohols has been conducted with Candida antarctica lipase B (CALB) and ruthenium catalyst 1. The optically pure allylic acetates obtained were subjected to oxidative cleavage to
Remote stereocontrol mediated by a sulfinyl group: Synthesis of allylic alcohols via chemoselective and diastereoselective reduction of γ-methylene δ-ketosulfoxides
Ruano, Jose L. Garcia,Fernandez-Ibanez, M. Angeles,Fernandez-Salas, Jose A.,Maestro, M. Carmen,Marquez-Lopez, Pablo,Rodriguez-Fernandez, M. Mercedes
experimental part, p. 1200 - 1204 (2009/07/18)
The efficiency of the sulfinyl group as a remote controller of the chemoselectivity and diastereoselectivity of the reduction of α,β-unsaturated α-[2-(p-tolylsulfinyl)phenyl] substituted ketones 1 has been demonstrated in reactions carried out under NaBH
Kinetic Resolution of Chiral Unsaturated Alcohols That Cannot Be Resolved Efficently via Enantioselective Epoxidation
Burgess, Kevin,Jennings, Lee D.
, p. 7434 - 7435 (2007/10/02)
-