129656-74-2Relevant academic research and scientific papers
Nucleophilic Aromatic Substitution on 1-Alkoxy-2-naphthoates with 1-Naphthyl Grignard Reagents. A Practical and Convenient Asymmetric Synthesis of 1,1'-Binaphthyl-2-carboxylates
Hattori, Tetsutaro,Hotta, Hiroki,Suzuki, Takatsugu,Miyano, Sotaro
, p. 613 - 622 (2007/10/02)
1-Naphthyl Grignard reagents efficiently displace the 1-alkoxyl group of 1-alkoxy-2-naphthoic esters to provide an easy access to the corresponding 1,1'-binaphthyl-2-carboxylates in excellent yields; isopropyl ester is bulky enough to prevent the Grignard
An Efficient Asymmetric Synthesis of Atropisomeric 1,1'-Binaphthyls via Nucleophilic Aromatic Substitution Reaction
Suzuki, Takatsugu,Hotta, Hiroki,Hattori, Tetsutaro,Miyano, Sotaro
, p. 807 - 810 (2007/10/02)
High levels of asymmetric induction (up to 98percent optical yield) were achieved in the joining of two naphthalene rings by the nucleophilic displacement of 1-menthoxyl group of 1-(-)-menthoxy-2-naphthoates (1) with 1-naphthyl Grignard reagents.Also repo
