129665-10-7Relevant academic research and scientific papers
A new method for generation and intramolecular diels-alder reaction of N-acyl and N-alkoxycarbonyl-1-aza-1,3-butadibnes. A one-pot synthesis of 1,7,8,8a-tetrahydro-3(2H)-indolizinones and 1,2,3,8,9,9a-hexahydro-4(4h)-quinolinones from α,β-unsaturated aldehydes
Uyehara, Tadao,Suzuki, Ichiro,Yamamoto, Yoshinori
, p. 3753 - 3756 (2007/10/02)
A one-pot transformation, made up of i) generation of N-trimethylsilylaldimines from α,β-unsaturated aldehyde, ii) exchange of the silyl group by acyl and oxycarbonyl groups, and iii) intramolecular Diels-Alder reaction of the resulting ψ′,ω′-unsaturated N-acyl-and a related N-oxycarbonyl-1-aza-1-3-butadienes in boiling xylene, gave 1,7,8,8a-tetrahydro-3(2H)-indolizinones (5), the 2-oxa derivatives of 5, and 1,2,3,8,9,9a-hexahydro-4(4H)-quinolizinones in practical yields.
The Diels-Alder Reaction of 1-Azadienes. The Effect of an α-Cyano Substituent
Teng, Min,Fowler, Frank W.
, p. 2481 - 2484 (2007/10/02)
N-Acyl-α-cyano-1-azadienes have been observed to be reactive and anti selective dienes in the intramolecular hetero Diels-Alder reaction.
