129762-86-3Relevant academic research and scientific papers
A convenient synthesis of alkynylsilanes by silylation of copper(I) alkynides
Sugita, Hikaru,Hatanaka, Yasuo,Hiyama, Tamejiro
, p. 379 - 380 (1996)
Alkynylation of chlorosilanes with copper(I) alkynides takes place smoothly in the presence of triphenylphosphine, N, N, N′, N′-tetramethylethylenediamine, or zinc powder to give a variety of alkynylsilanes in good yields.
Preparation of novel photoluminescent oligocarbosilanes by hydrosilylation [4]
Gradwell, Sheila E.,Kepler, Cindy L.
, p. 2871 - 2872 (2002)
The preparation of the photoluminescent oligocarbosilanes by hydrosilylation was discussed. Karstedt-catalyzed oligomerization of photoluminescent oligocarbosilanes was carried out in an argon atmosphere in a sealed pressure tube. The initially colorless monomer became dark brown within one minute after addition of catalysts. The photoluminescent polymers offer flexibilities in molecular design and good processability. Their luminescent properties could be tuned at the molecular level. The photoluminescent oligocarbosilanes are unique because they contain both conjugated and cross conjugated segments.
B(C6F5)3/Amine-Catalyzed C(sp)?H Silylation of Terminal Alkynes with Hydrosilanes: Experimental and Theoretical Studies
Ma, Yuanhong,Lou, Shao-Jie,Luo, Gen,Luo, Yong,Zhan, Gu,Nishiura, Masayoshi,Luo, Yi,Hou, Zhaomin
, p. 15222 - 15226 (2018)
Transition metal catalyzed C?H functionalization of organic compounds has proved to be a useful atom-efficient strategy in organic synthesis. In contrast, main-group-element-based catalytic processes for C?H functionalization have remained underexplored t
Polymeric organosilicon systems. XXIII. Synthesis and photochemical and thermal properties of (E)- and (Z)-poly
Ohshita, Joji,Kanaya, Daisuke,Watanabe, Tsuguo,Ishikawa, Mitsuo
, p. 165 - 174 (2007/10/02)
(E)-Poly, (E)-poly, (E)-poly, (E)-poly, and (Z)-poly(1,2
Copper(I) chloride catalyzed cross-dehydrocoupling reactions between silanes and ethynyl compounds. A new method for the copolymerization of silanes and alkynes
Liu, Hua Qin,Harrod, John F.
, p. 1100 - 1105 (2007/10/02)
In the presence of an amine, copper(I) chloride is an effective catalyst for the cross-dehydrocoupling of silanes with alkynes.The reactions proceed at useful rates above 100 deg C, but rates drop dramatically on going from 1o to 2o
