129762-86-3Relevant articles and documents
A convenient synthesis of alkynylsilanes by silylation of copper(I) alkynides
Sugita, Hikaru,Hatanaka, Yasuo,Hiyama, Tamejiro
, p. 379 - 380 (1996)
Alkynylation of chlorosilanes with copper(I) alkynides takes place smoothly in the presence of triphenylphosphine, N, N, N′, N′-tetramethylethylenediamine, or zinc powder to give a variety of alkynylsilanes in good yields.
B(C6F5)3/Amine-Catalyzed C(sp)?H Silylation of Terminal Alkynes with Hydrosilanes: Experimental and Theoretical Studies
Ma, Yuanhong,Lou, Shao-Jie,Luo, Gen,Luo, Yong,Zhan, Gu,Nishiura, Masayoshi,Luo, Yi,Hou, Zhaomin
, p. 15222 - 15226 (2018)
Transition metal catalyzed C?H functionalization of organic compounds has proved to be a useful atom-efficient strategy in organic synthesis. In contrast, main-group-element-based catalytic processes for C?H functionalization have remained underexplored t
Copper(I) chloride catalyzed cross-dehydrocoupling reactions between silanes and ethynyl compounds. A new method for the copolymerization of silanes and alkynes
Liu, Hua Qin,Harrod, John F.
, p. 1100 - 1105 (2007/10/02)
In the presence of an amine, copper(I) chloride is an effective catalyst for the cross-dehydrocoupling of silanes with alkynes.The reactions proceed at useful rates above 100 deg C, but rates drop dramatically on going from 1o to 2o
