A convenient synthesis of alkynylsilanes by silylation of copper(I) alkynides

DOI: 10.1246/cl.1996.379

Source and publish data:

Chemistry Letters p. 379 - 380 (1996)

Update date:2022-08-10

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Authors:

Sugita, Hikaru

Hatanaka, Yasuo

Hiyama, Tamejiro

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Article abstract of DOI:10.1246/cl.1996.379

Alkynylation of chlorosilanes with copper(I) alkynides takes place smoothly in the presence of triphenylphosphine, N, N, N′, N′-tetramethylethylenediamine, or zinc powder to give a variety of alkynylsilanes in good yields.

Full text of DOI:10.1246/cl.1996.379

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