1300116-86-2

Upstream product

• 118620-86-3 (2S,3S)-4-(p-methoxybenzyloxy)-2,3-(isopropylidenedioxy)-butan-1-ol 
• 118620-85-2 (2R)-1-(4-methoxybenzyloxy)but-3-yn-2-ol 
• 118620-84-1 (4R,5S)-[(4-methoxybenzyloxy)methyl]-5-chloromethyl-2,2-dimethyl-1,3-dioxolane 

Downstream Products

• 1300116-90-8 N-benzyl-N-{(3S)-3-[(tert-butyldiphenylsilyl)oxy]-4-(4-methoxybenzyloxy)but-1-ynyl}-4-methylbenzenesulfonamide 
• 1300116-94-2 N-benzyl-N-[(3S)-3-hydroxy-4-(4-methoxybenzyloxy)but-1-ynyl]-4-methylbenzenesulfonamide 
• 1029537-45-8 N-benzyl-N-[(E)-(3S)-3-hydroxy-4-(4-methoxybenzyloxy)but-1-enyl]-4-methylbenzenesulfonamide 
• 1029537-47-0 N-benzyl-N-{(3R)-(E)-3-(prop-2-ynyl)oxy-4-[(4-methoxybenzyl)oxy]but-1-enyl}-4-methylbenzenesulfonamide 
• 1029537-49-2 N-benzyl-N-[(E)-(R)-1-((S)-1-hydroxy-3-trimethylsilylprop-2-ynyl)-4-(4-methoxybenzyloxy)but-2-enyl]-4-methylbenzenesulfonamide 
• 1029537-52-7 N-benzyl-N-{(1R,2R)-2-hydroxy-3-oxo-1-[(E)-3-(4-methoxybenzyloxy)prop-1-ene]butyl}-4-methylbenzenesulfonamide 
• 1300117-59-2 (1S,2R)-(E)-2-(N-benzyl-4-methylbenzenesulfonylamino)-5-(4-methoxybenzyloxy)-1-(trimethylsilyl)pent-3-enyl (S)-2-methoxy-2-phenylacetate 
• 1300117-60-5 (1S,2R)-(E)-2-(N-benzyl-4-methylbenzenesulfonylamino)-5-(4-methoxybenzyloxy)-1-(trimethylsilyl)pent-3-enyl (R)-2-methoxy-2-phenylacetate 

Relevant academic research and scientific papers

Synthesis of 1,2-amino alcohols by sigmatropic rearrangements of 3-(N-Tosylamino)allylic alcohol derivatives

Sigmatropic rearrangements of 3-(N-tosylamino)allylic alcohol derivatives, a particular subclass of functionalized enamides, have been investigated. Whereas the presence of the nitrogen atom alters the stereochemical outcome of Ireland-Claisen rearrangeme

Synthesis of optically enriched 1,2-aminoalcohols by [2,3]-Wittig rearrangements of 3-aza-allylic alcohol derivatives

[2,3]-Wittig rearrangements of (E)-3-aza-allylic alcohol derivatives can provide access to syn or anti optically enriched 1,2-aminoalcohols by using a chirality transfer or a chiral auxiliary.