130059-81-3

Basic information

• Product Name: Methanone, (4-methoxyphenyl)[(2R,3S)-3-phenyloxiranyl]-
• CAS NO: 130059-81-3
• Molecular Formula: C16H14O3
• Molecular Weight: 254.285
• Mol File: 130059-81-3.mol
• Article Data: 42

Chemical Properties

• CAS DataBase Reference: Methanone, (4-methoxyphenyl)[(2R,3S)-3-phenyloxiranyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (4-methoxyphenyl)[(2R,3S)-3-phenyloxiranyl]-(130059-81-3)
• EPA Substance Registry System: Methanone, (4-methoxyphenyl)[(2R,3S)-3-phenyloxiranyl]-(130059-81-3)

Safety Data

• Hazardous Substances Data: 130059-81-3(Hazardous Substances Data)

Upstream product

• 22966-19-4 trans-4'-methoxychalcone 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 100-52-7 benzaldehyde 
• 959-23-9 4'-methoxychalcone 

Downstream Products

• 959-23-9 4'-methoxychalcone 
• 32664-28-1 3-(4-methoxyphenyl)-5-phenyl-1H-pyrazole 
• 4927-44-0 5-Benzyl-5-(4-methoxy-phenyl)-imidazolidine-2,4-dione 
• 4136-21-4 p-methoxybenzoylmethanol 
• 111008-99-2 3-hydroxy-1-(4-methoxy-phenyl)-3-phenyl-propan-1-one 
• 93011-61-1 3-(4-methoxyphenyl)-3-oxo-2-phenylpropanal 
• 99442-76-9 3-Fluoro-2-hydroxy-1-(4-methoxy-phenyl)-3-phenyl-propan-1-one 
• 22464-03-5 threo-3-Chlor-2-hydroxy-1-(4-methoxyphenyl)-3-phenyl-propan-1-on 
• 22464-03-5 erythro-3-Chlor-2-hydroxy-1-(4-methoxyphenyl)-3-phenyl-propan-1-on 
• 127634-33-7 3-Bromo-2-hydroxy-1-(4-methoxy-phenyl)-3-phenyl-propan-1-one 
• 132455-51-7 (2S,3R)-3-Phenyl-oxirane-2-carboxylic acid 4-methoxy-phenyl ester 
• 70265-89-3 (4S,5R)-3-(4-Methoxy-phenyl)-5-phenyl-4,5-dihydro-isoxazol-4-ol 

Relevant articles and documents

Highly enantioselective epoxidation of 2,4-diarylenones by using dimeric cinchona phase-transfer catalysts: Enhancement of enantioselectivity by surfactants

Dramatic increases in reaction rates and enantioselectivities can be effected by the use of surfactants for the phase-transfer catalytic epoxidation of aromatic enones. Based on the X-ray crystal structure of the most effective catalyst-a modified cinchona alkaloid-a plausible transition state of the reaction has been modeled (see picture; HOO- yellow, C gray, H white, N blue, O red).

Heterogenization of Shibasaki's binol/La catalyst for enantioselective epoxidation of α,β-unsaturated ketones with multitopic binol ligands: The impact of bridging spacers

(Figure Presented) Bridging the gap: Heterogenized Shibasaki's binol/La catalyst is synthesized by a self-supporting strategy through the reactions of multitopic ligands with La(OiPr)3 (see picture). The catalyst shows high activity and enantioselectivity, and can be reused in the asymmetric epoxidation of α,β-unsaturated ketones.

Asymmetric epoxidation of α,β-unsaturated ketones catalyzed by rare-earth metal amides RE[N(SiMe3)2]3with chiral TADDOL ligands

The catalytic asymmetric epoxidation of α,β-unsaturated ketones by tert-butylhydroperoxide (TBHP) has been well established using rare-earth metal amides RE[N(SiMe3)2]3 (RE = La(1), Nd(2), Sm(3), Y(4), Yb(5)) with chiral TADDOL ligands. It was found that

Ligand regulation for manganese-catalyzed enantioselective epoxidation of olefins without acid

A novel manganese catalyst bearing an l-proline-derived N4 ligand has been developed for enabling acid-free asymmetric epoxidation of olefins with tert-butyl hydroperoxide as the oxidant. A variety of olefins that are well-matched in size with the ligand