131721-92-1

Basic information

• Product Name: Benzene, [[(4E)-4-hexenyloxy]methyl]-
• CAS NO: 131721-92-1
• Molecular Formula: C13H18O
• Molecular Weight: 190.285
• Mol File: 131721-92-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, [[(4E)-4-hexenyloxy]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[(4E)-4-hexenyloxy]methyl]-(131721-92-1)
• EPA Substance Registry System: Benzene, [[(4E)-4-hexenyloxy]methyl]-(131721-92-1)

Safety Data

• Hazardous Substances Data: 131721-92-1(Hazardous Substances Data)

Upstream product

• 928-92-7 (E)-hex-4-en-1-ol 
• 100-39-0 benzyl bromide 
• 100-44-7 benzyl chloride 
• 51368-03-7 hex-4-enoic acid ethyl ester 
• 59137-50-7 6-benzyloxy-1-hexene 

Downstream Products

• 144693-97-0 6-Benzyloxy-2-hydroxy-3-vinyl-hexanoic acid methyl ester 
• 144694-09-7 2-Hydroxy-3-(tetrahydro-furan-2-yl)-butyric acid methyl ester 
• 144694-02-0 (E)-7-Benzyloxy-2-hydroxy-3-methyl-hept-4-enoic acid methyl ester 
• 144694-09-7 methyl 2-hydroxy-3-(2-oxolane)-butanoate 
• 144694-02-0 (E)-(2S,3S)-7-Benzyloxy-2-hydroxy-3-methyl-hept-4-enoic acid methyl ester 
• 114524-26-4 2-methyl-3-(phenylselanyl)tetrahydro-2H-pyran 
• 61103-84-2 benzyl hexyl ether 
• 1300655-88-2 C₂₄H₃₆O₂Si 
• 1300655-87-1 C₁₆H₂₂O₂ 
• 1300655-93-9 C₂₇H₄₄O₆Si 
• 1300655-92-8 C₂₈H₄₆O₅Si 
• 1300655-91-7 C₂₇H₄₈O₄Si 

Relevant articles and documents

METHODS OF BORYLATION AND USES THEREOF

The present invention relates, in general terms, to methods of borylation and uses thereof. In particular, the present invention provides a method of borylating an alkene compound by contacting the compound with a boron compound, a Fe pre-catalyst and a protic additive. The borylation occurs at a vicinal (β) position to an electron donating or electron withdrawing moiety of the compound.

Tandem ring-closing metathesis/transfer hydrogenation: Practical chemoselective hydrogenation of alkenes

An operationally simple chemoselective transfer hydrogenation of alkenes using ruthenium metathesis catalysts is presented. Of great practicality, the transfer hydrogenation reagents can be added directly to a metathesis reaction and effect hydrogenation of the product alkene in a single pot at ambient temperature without the need to seal the vessel to prevent hydrogen gas escape. The reduction is applicable to a range of alkenes and can be performed in the presence of aryl halides and benzyl groups, a notable weakness of Pd-catalyzed hydrogenations. Scope and mechanistic considerations are presented.

Enantioselective microbial hydrolysis of dissymmetrical cyclic carbonates with disubstitution

Enantioselective microbial hydrolysis of C1 and C2 dissymmetrical cyclic carbonates with disubstitution (methyl and another groups) has been developed. Pseudomonas diminuta (FU0090), a bacterium, efficiently catalyzes the hydrolysis of five-membered cyclic carbonates. While the trans-substrates are hydrolyzed with low enantioselectivities and/or reactivities, the microbe hydrolyzes the cis-substrates with very high enantioselectivities to afford the corresponding almost optically pure anti-(2R,3S)-diols. On the other hand, six-membered trans-cyclic carbonates are enantioselectively hydrolyzed to afford the corresponding optically active syn-(2R,4R)-diols, although the hydrolysis of the cis-substrates gives racemic compounds. In all cases, the enzyme prefers the (R)-enantiomer for the carbon atom bearing a methyl group.