130149-45-0Relevant academic research and scientific papers
Cationic Rearrangements of 2-Azabicycloheptane Systems. - NMR and MS Methods for the Analysis of 17O- or 18O-Labelled Compounds
Franzisket, Ludwig,Heesing, Albert
, p. 691 - 700 (2007/10/02)
O-Tosylation of 2-hydroxy-2-azabicyclohept-6-ene and -heptane results in rearrangements to 1-aza- systems.The regioselectivity is caused by kinetic control.High stereoselectivity, partial scrambling of the O-label and low yields in cross-ove
Regio- and Stereoselectivity in Anionic Ring Opening Reactions of 2-Azabicycloheptane Derivatives
Franzisket, Ludwig,Heesing, Albert
, p. 635 - 643 (2007/10/02)
In the regioselective ring opening of 1 via the dianion 1c the intermediacy of 2a is proven by labeling experiments.The regioselective cleavage of the four-membered ring in 3 by LiAlH4 proceeds stereoselectively both in the ring and the side chain positio
