130339-80-9Relevant academic research and scientific papers
Addition of Polyfunctional and Pure (E or Z) Alkenylcopper and Arylcopper Compounds to Alkylidenemalonates
Cahiez, Gerard,Venegas, Patricia,Tucker, Charles E.,Majid, Tahir N.,Knochel, Paul
, p. 1406 - 1408 (2007/10/02)
Polyfunctional and stereochemically pure (E) or (Z) alkenylcopper reagents have been generated by carbocupration of terminal alkynes or by an iodine-lithium exchange reaction and have been found to add to various diethyl alkylidenemalonates, affording γ,δ
A new preparation of highly functionalized aromatic and heteroaromatic zinc and copper organometallics
Majid,Knochel
, p. 4413 - 4416 (2007/10/02)
Functionalized aromatic iodides possessing an ester, cyano, chloride or keto group can be converted to arylzinc iodides by reaction with zinc in DMF or DMAC. After transmetallation to the corresponding arylcopper, they react with several electrophiles suc
