130378-33-5

Basic information

• Product Name: Ru(CH₃C₆H₄NHCHC₆H₂CH₃O)(P(C₆H₅)3)2Cl(CO)
• Synonyms: Ru(CH₃C₆H₄NHCHC₆H₂CH₃O)(P(C₆H₅)3)2Cl(CO)
• CAS NO: 130378-33-5
• Molecular Weight: 913.397
• Mol File: 130378-33-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Ru(CH₃C₆H₄NHCHC₆H₂CH₃O)(P(C₆H₅)3)2Cl(CO)(CAS DataBase Reference)
• NIST Chemistry Reference: Ru(CH₃C₆H₄NHCHC₆H₂CH₃O)(P(C₆H₅)3)2Cl(CO)(130378-33-5)
• EPA Substance Registry System: Ru(CH₃C₆H₄NHCHC₆H₂CH₃O)(P(C₆H₅)3)2Cl(CO)(130378-33-5)

Safety Data

• Hazardous Substances Data: 130378-33-5(Hazardous Substances Data)

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 
• 92962-93-1 2-formyl-4-methyl-6-((p-tolylimino)methyl)phenol 
• 7647-01-0 hydrogenchloride 
• 56-34-8 tetraethylammonium chloride 

Downstream Products

• 591781-72-5 [Ru(η1-C6H2OH-2-CHNC6H4Me(p)-3-Me-5)(PPh3)2(CO)(2,2'-bipyridine)](PF6) 
• 591781-78-1 [Ru(η1-C6H2OH-2-CHNC6H4Me(p)-3-Me-5)(PPh3)2(CO)(1,10-phenanthroline)](PF6) 
• 591781-84-9 [Ru(η1-C6H2OH-2-CHNC6H4Me(p)-3-Me-5)(PPh3)2(CO)(2-(2-pyridyl)benzthiazole)](PF6) 
• 188547-23-1 [Ru(CO)(P(C₆H₅)3)2(O₂CC₆H₄CH₃)(C₁₅H₁₄NO)] 
• 188547-24-2 carbonyl(p-chlorobenzoato)[4-methyl-6-(N-p-tolyliminomethyl)phenol-C⁽²⁾]bis(triphenylphosphine)ruthenium(II) 
• 184299-80-7 carbonyl(nitrato)[4-methyl-6-(N-(p-tolyl)imino)phenol-C⁽²⁾]bis(triphenylphosphine)ruthenium(II) 
• 336142-03-1 [Ru(CH₃C₆H₄NHCHC₆H₂(CH₃)(O)C(C₆H₅)CH)(P(C₆H₅)3)2(CO)Cl] 
• 336142-18-8 [Ru(CH₃C₆H₄NHCHC₆H₂(CH₃)(O)C(CH₂OH)CH)(P(C₆H₅)3)2(CO)Cl] 
• 336142-28-0 [Ru(CH₃OC₆H₄NHCHC₆H₂(CH₃)(O)C(CH₂OH)CH)(P(C₆H₅)3)2(CO)Cl] 
• 336142-23-5 [Ru(ClC₆H₄NHCHC₆H₂(CH₃)(O)C(CH₂OH)CH)(P(C₆H₅)3)2(CO)Cl] 

Relevant articles and documents

Acetylacetonato chelated ruthenium organometallics incorporating imine-phenol function: Spectroscopic, structural, electrochemical and cytotoxicity studies

The heterogeneous phase reaction of Ru(η2-RL)(PPh3)2(CO)Cl, 1 with lithium acetylacetonate (Liacac) afforded the complexes of the type Ru(η1-RL)(PPh3)2(CO)(acac), 2 in excellent yield where

Decarbonylative metalation of diformylphenol Schiff bases: New osmium and ruthenium organometallics incorporating the iminium-phenolato zwitterionic motif

The reaction of Schiff bases of 2,6-diformyl-4-methylphenol with M(PPh3)3X2 in ethanol has afforded carbonylhalo[4-methyl-6-(N-R-iminiomethyl)phenolato-C 2,O]bis(triphenylphosphine)metal(II) compounds, MII(RL)(PPh3)2(CO)X (M = Os, X = Br; M = Ru, X = Cl; R = alkyl, aryl). The process is believed to proceed via oxidative addition of the aldehydic C(O)-H bond to the metal followed by CO extrusion and reductive proton elimination. The X-ray structure of Os(EtL)(PPh3)2(CO)Br·CH2Cl2 has revealed the presence of the distorted octahedral OsC2P2BrO coordination sphere. In the four-membered, Os(C,O) chelate ring, the metal atom is bonded to the carbon site to which an aldehyde group was attached in the parent ligand. The presence of the iminium-phenolato zwitterionic motif is consistent with the N?O length as well as with IR and 1H NMR spectra. Bond parameters of the osmium and ruthenium systems are compared. Significant dπ-pπ back-bonding with the metalated aromatic ring occurs in the case of osmium. The complexes display a quasi-reversible one-electron cyclic voltammetric couple (E1/2 = 0.50-0.70 V), but the oxidized congeners are too unstable to be isolated. Upon reaction of M(RL)(PPh3)2(CO)X with carboxylates, the latter gets chelated, the M-O(phenolato) linkage is cleaved, and the iminium-phenolato function tautomerizes to the imine-phenol function.