130409-81-3

Basic information

• Product Name: ethyl (2,2-difluoro-2-phenylsulfinyl)acetate
• Synonyms: ethyl (2,2-difluoro-2-phenylsulfinyl)acetate
• CAS NO: 130409-81-3
• Molecular Weight: 264.25
• Mol File: 130409-81-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: ethyl (2,2-difluoro-2-phenylsulfinyl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (2,2-difluoro-2-phenylsulfinyl)acetate(130409-81-3)
• EPA Substance Registry System: ethyl (2,2-difluoro-2-phenylsulfinyl)acetate(130409-81-3)

Safety Data

• Hazardous Substances Data: 130409-81-3(Hazardous Substances Data)

Upstream product

• 54882-04-1 ethyl 2-(phenylsulfinyl)acetate 
• 108-98-5 thiophenol 
• 101068-11-5 ethyl 2,2-difluoro-2-(phenylthio)acetate 
• 7031-27-8 (phenylthio)acetic acid chloride 
• 7605-25-6 ethyl phenylsulfenylacetate 
• 75850-40-7 ethyl (phenylsulfonyl)sodioacetate 

Downstream Products

• 122590-86-7 2,2-difluoro-1-phenyl-2-(phenylsulfonyl)ethan-1-ol 
• 861721-51-9 1-(benzenesulfonyl)difluoromethyl-3-phenylpropanol 
• 861721-49-5 (E)-1,1-difluoro-4-phenyl-1-(phenylsulfonyl)but-3-en-2-ol 
• 122590-90-3 α-(difluoromethyl)-2-furanmethanol 
• 871504-64-2 2,2-difluoro-1-(naphthalen-2-yl)-2-(phenylsulfonyl)ethan-1-ol 
• 122590-89-0 1-(4-chlorophenyl)-2,2-difluoro-2-(phenylsulfonyl)ethan-1-ol 
• 122590-87-8 2,2-difluoro-1-(4-methoxyphenyl)-2-(phenylsulfonyl)ethan-1-ol 
• 122590-88-9 2,2-difluoro-1-(4-methylphenyl)-2-phenylsulfonylethanol 

Relevant articles and documents

Decarboxylative nucleophilic difluoromethylation of aldehydes and imines

The high demand for the biologically active CF2H-molecules has stimulated significant efforts to develop efficient methods for the installation of CF2H functionality. We found that phenylsulfonyl difluoroacetate salt (PhSO2/sub

Aryl sulfuryl difluoroacetic salt compound, as well as preparation method and application thereof

The invention discloses an aryl sulfuryl difluoroacetic salt compound, as well as a preparation method and application thereof. The aryl sulfuryl difluoroacetic salt compound reacts with aldehyde at room temperature to obtain an aryl sulfuryl substituted alpha-difluoromethyl alcohol compound. The aryl sulfuryl difluoroacetic salt compound has the beneficial effects of mild reaction condition, high product yield, few side effect and high universality when the aryl sulfuryl difluoroacetic salt compound is adopted to prepare the aryl sulfuryl substituted alpha-difluoromethyl alcohol compound.

α-Fluorination of methyl phenyl sulfoxide and related compounds by molecular fluorine: A novel method for the introduction of fluorine into sulfoxides bearing α-H atoms

Direct formation of α-fluorosulfones from sulfoxides bearing α-H atoms merely by reaction with molecular fluorine (5% F2/N2) is reported, and a novel non-Pummerer-type mechanism is proposed for this α-fluorination reaction.