130412-98-5

Basic information

• Product Name: C₂₆H₂₅NP⁽¹⁺⁾*I^(1-)
• Synonyms: C₂₆H₂₅NP⁽¹⁺⁾*I^(1-)
• CAS NO: 130412-98-5
• Molecular Weight: 509.369
• Mol File: 130412-98-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₂₆H₂₅NP⁽¹⁺⁾*I^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₂₅NP⁽¹⁺⁾*I^(1-)(130412-98-5)
• EPA Substance Registry System: C₂₆H₂₅NP⁽¹⁺⁾*I^(1-)(130412-98-5)

Safety Data

• Hazardous Substances Data: 130412-98-5(Hazardous Substances Data)

Upstream product

• 620-05-3 iodomethylbenzene 
• 17986-01-5 N-methyl-P,P,P-triphenylphosphine imide 
• 603-35-0 triphenylphosphine 
• 124316-00-3 1-<<(Triphenylphosphoranylidene)amino>methyl>benzotriazole 
• 74-88-4 methyl iodide 
• 52826-45-6 (benzylimino)triphenylphosphorane 
• 15729-44-9 amino(triphenyl)phosphonium chloride 
• 13916-35-3 lithium triphenylphosphonium azayldiide 

Downstream Products

• 103-67-3 benzyl-methyl-amine 

Relevant articles and documents

1-(Triphenylphosphorylideneaminomethyl)benzotriazole (BETMIP) a Novel +CH2N= Synthetic Equivalent: Its Application to the Synthesis of Carbodiimides, Imines, Isothiocyanates, Aziridines, and Secondary Amines

One-carbon homologation has been achieved in novel syntheses of the title compounds by one-pot reaction of 1-(triphenylphosphorylideneaminomethyl)benzotriazole (1) with Grignard reagents followed by in situ transformations of the phosphorazene functionality with isocyanates, aldehydes, carbon disulfide, ethylene oxide, and alkyl halides, respectively.