13916-35-3

Upstream product

• 603-35-0 triphenylphosphine 
• 15729-44-9 amino(triphenyl)phosphonium chloride 
• 15931-69-8 bromure de triphenyl aminophosphonium 
• 2240-47-3 imino(triphenyl)phosphorane 

Downstream Products

• 126864-04-8 C₂₆H₃₂NP 
• 41309-08-4 Ethyl(triphenylphosphoranylidene)sulfamate 
• 126864-10-6 N-Methyl-N-propylamino-triphenyl-phosphonium-jodid 
• 126863-98-7 bromure de triphenyl N,N-isoindolinyl-2 phosphonium 
• 110-68-9 N-n-butyl-N-methylamine 
• 52427-90-4 N-propionyltriphenylphosphinimine 
• 126864-02-6 tetraphenylborate de triphenyl N,N-bis- aminophosphonium 
• 139007-24-2 tris(tert-butylimido)(triphenylphosphineiminato)rhenium(VII) 
• 126864-14-0 C₂₉H₃₁NP⁽¹⁺⁾*I^(1-) 

Relevant academic research and scientific papers

Reactivity of Ph3PNLi towards PIII and PV electrophiles

A study of the reactivity of Ph3P{double bond, long}NLi towards phosphorus electrophiles allowed us to develop a general method to isolate, or cleanly generate in situ, a broad family of polyphosphinimines displaying P{double bond, long}N-P bon

Convenient one pot preparation of acylated phosphinimines and aminophosphonium salts from the versatile triphenylphosphonium and lithium azayldiide Ph3P=N-Li

Starting from gaseous ammonia, through two multisteps reactions, either acylation or alkylation reactions, we have access to different N-substituted aminophosphonium salts, precursors of amines. Preparation and use of the intermediate, the triphenylphosph

PHOSPHONIUM DIAZA-DIYLIDS AND AZA-YLDIID AS NEW AND EFFICIENT REAGENTS FOR PRIMARY AND SECONDARY AMINES SYNTHESIS

Metallated aminophosphonium ylids, diaza-diylids and aza-yldiid, are investigated as reagents for primary and secondary amines synthesis.

Alkylation et acylation de la triphenylphosphinimine N-lithiee

A new synthetic approach to primary and secondary amines using N-lithiated triphenylphosphinimine is reported.This key reagent, accessible in two steps from dibromortiphenylphosphorane and ammonia, when treated with electrophiles yields N-substituted triphenylphosphinimine derivatives.These can react to give N-mono or disubstituted triphenylphosphonium salts which upon hydrolysis lead to the corresponding primary and secondary amines.

L'AZA-YLURE N-LITHIE (C6H5)3P=NLi, REACTIF D'AMINATION

The preparation of the lithiated aza-ylide 3 has been improved and its one-pot reactivity toward alkyl and acyl halides to give amino-phosphonium salts and accordingly amines is described.