13042-00-7 Usage
Description
[(Z)-3-chloroprop-2-enyl] acetate, also known as allyl 3-chloropropionate, is a chemical compound with the formula C5H7ClO2. It is a colorless to pale yellow liquid with a pungent odor and is soluble in organic solvents. [(Z)-3-chloroprop-2-enyl] acetate is known for its versatile applications across different industries due to its unique properties.
Uses
Used in Flavor and Fragrance Industry:
[(Z)-3-chloroprop-2-enyl] acetate is used as a flavoring agent for enhancing the taste and aroma of various food and beverage products. Its ability to add a unique and pleasant flavor makes it a valuable component in the industry.
Used in Perfume and Personal Care Products:
In the perfume and personal care products industry, [(Z)-3-chloroprop-2-enyl] acetate is used as a fragrance ingredient. Its pungent odor and solubility in organic solvents make it an ideal choice for creating long-lasting and appealing scents in perfumes and other personal care items.
Used in Pharmaceutical Production:
[(Z)-3-chloroprop-2-enyl] acetate is also utilized in the production of pharmaceuticals. Its chemical properties allow it to be a key component in the synthesis of various drugs, contributing to the development of new medications and therapies.
Used in Chemical Production:
[(Z)-3-chloroprop-2-enyl] acetate is further employed in the production of other chemicals, showcasing its versatility and importance in the chemical industry. Its ability to be a part of various chemical reactions and processes makes it a valuable asset in creating a wide range of products.
However, it is essential to note that exposure to [(Z)-3-chloroprop-2-enyl] acetate can cause irritation to the skin, eyes, and respiratory system, and it may be harmful if swallowed or inhaled. Therefore, it should be handled with care and safety guidelines should be followed when using it.
Check Digit Verification of cas no
The CAS Registry Mumber 13042-00-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,0,4 and 2 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 13042-00:
(7*1)+(6*3)+(5*0)+(4*4)+(3*2)+(2*0)+(1*0)=47
47 % 10 = 7
So 13042-00-7 is a valid CAS Registry Number.
InChI:InChI=1/C5H7ClO2/c1-5(7)8-4-2-3-6/h2-3H,4H2,1H3/b3-2-
13042-00-7Relevant articles and documents
Phenylselenium Trichloride in Organic Synthesis. Reaction with Unsaturated Compounds. Preparation of Vinylic Chlorides via Selenoxide Elimination
Engman, Lars
, p. 4086 - 4094 (2007/10/02)
Phenylselenium trichloride, PhSeCl3, was reacted with a number olefinic compounds to produce (β-chloroalkyl)phenylselenium dichlorides.The addition was anti stereospecific and irreversible.The presence of an oxygen substituent (acyloxy or aryloxy group) in the allylic position of the olefin directed the attack of PhSeCl3 to occur regiospecifically anti-Markovnikov to give a (β-acyloxy/aryloxy-β'-chloroalkyl)phenylselenium dichloride.When the (β-chloroalkyl)phenylselenium dichlorides were treated in methylene chloride with aqueous sodium hydrogen carbonate, the selenium dichloride moiety was readily hydrolyzed to a selenoxide, which underwent the usual selenoxide elimination reaction to produce an allylic or a vinylic chloride.Symmetrical olefins containing no allylic hydrogens were converted to vinylic chlorides with retention of olefin geometry.Olefins containing a directing oxygen substituent in the allylic position afforded vinylic chlorides where the vinylic halogen atom was oriented 1,3 to the oxygen substituent (E/Z mixture).Other olefins afforded mixtures of allylic and vinylic halides in varying proportions.The reaction of phenyselenium tribromide, PhSeBr3, with some olefinic compounds was also investigated.This material showed the same stereo- and regiochemical behavior as PhSeCl3 in its addition reactions.However, the adducts were not useful for the preparation of vinylic or allylic bromides by using the hydrolytic selenoxide elimination reaction.
