130481-19-5

Basic information

• Product Name: N-(1-Phenyl-1-trifluoromethyl-but-3-enyl)-hydroxylamine
• CAS NO: 130481-19-5
• Molecular Weight: 231.218
• Mol File: 130481-19-5.mol

Chemical Properties

• CAS DataBase Reference: N-(1-Phenyl-1-trifluoromethyl-but-3-enyl)-hydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(1-Phenyl-1-trifluoromethyl-but-3-enyl)-hydroxylamine(130481-19-5)
• EPA Substance Registry System: N-(1-Phenyl-1-trifluoromethyl-but-3-enyl)-hydroxylamine(130481-19-5)

Safety Data

• Hazardous Substances Data: 130481-19-5(Hazardous Substances Data)

Upstream product

• 655-25-4 2,2,2-trifluoroacetophenone oxime 
• 1730-25-2 allylmagnesium bromide 
• 106-95-6 allyl bromide 

Downstream Products

• 133367-66-5 1,1,1-trifluoro-2-phenylpent-4-en-2-amine 

Relevant articles and documents

Unusual reactivity of allylmagnesium bromide

Reaction of allylmagnesium bromide with trifluoromethyl oximes is different than with other Grignard reagents. On the other hand, allylmagnesium bromide acted as a reducing agent towards trifluoromethyl ketones. By using an excess of this Grignard reagent, an exclusive addition reaction is obtained. A single electron reaction is suggested to explain the reductive process.

OXIMES TRIFLUOROMETHYLEES ET ORGANOMAGNESIENS ALLYLIQUES: SYNTHESE D'HYDROXYLAMINES HOMOALLYLIQUES ET D'AMINES HOMOALLYLIQUES PRIMAIRES

Les organomagnesiens allyliques s'additionnent aux oximes substituees par un groupement trifluoromethyle, pour conduire a des hydroxylamines avec des rendements eleves.Une telle reaction est particuliere a ces oximes et a ces magnesiens.Les hydroxylamines obtenues ont ete transformees en amines primaires homoallyliques.