Unusual reactivity of allylmagnesium bromide

DOI: 10.1016/S0040-4039(00)97564-6

Source and publish data:

Tetrahedron Letters p. 4143 - 4144 (1990)

Update date:2022-08-04

Topics:

Authors:

Felix, Caroline

Laurent, Andre

Mison, Pierre

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Article abstract of DOI:10.1016/S0040-4039(00)97564-6

Reaction of allylmagnesium bromide with trifluoromethyl oximes is different than with other Grignard reagents. On the other hand, allylmagnesium bromide acted as a reducing agent towards trifluoromethyl ketones. By using an excess of this Grignard reagent, an exclusive addition reaction is obtained. A single electron reaction is suggested to explain the reductive process.

Full text of DOI:10.1016/S0040-4039(00)97564-6

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