Tetrahedron Letters p. 4143 - 4144 (1990)
Update date:2022-08-04
Topics:
Felix, Caroline
Laurent, Andre
Mison, Pierre
Reaction of allylmagnesium bromide with trifluoromethyl oximes is different than with other Grignard reagents. On the other hand, allylmagnesium bromide acted as a reducing agent towards trifluoromethyl ketones. By using an excess of this Grignard reagent, an exclusive addition reaction is obtained. A single electron reaction is suggested to explain the reductive process.
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