13049-99-5Relevant academic research and scientific papers
Potassium fluoride on alumina: A convenient synthesis of O-alkyl methyldithiocarbonates. Pyrolysis of O-benzyl-S-methyldithiocarbonates
Villemin, Didier,Hachemi, Messaoud
, p. 2449 - 2459 (2007/10/03)
Xanthates were easily prepared by adsorption of alcohol on KF-Al2O3 followed by treatment of carbon disulfide and iodomethane at room temperature. Pyrolysis of benzyl xanthate affords to a complex mixture of products. A radical process was proposed to explain the nature of products obtained.
4-DIMETHYLAMINOPYRIDINE N-OXIDE AS AN EXCELLENT CATALYST FOR THIONE TO THIOL REARRANGEMENT OF XANTHATES
Harano, Kazunobu,Kiyonaga, Hideo,Sugimoto, Shin-ichiro,Matsuoka, Toshikazu,Hisano, Takuzo
, p. 2327 - 2330 (2007/10/02)
4-Dimethylaminopyridine N-oxide effectively catalyzes the thione to hiol rearrangement of O,S-dialkyl dithiocarbonates (xanthates) to provide S,S-dialkyl dithiocarbonates.
