130550-50-4Relevant academic research and scientific papers
High Yield Reduction of 2-O-Trifluoromethanesulphonate Esters of α-Hydroxylactones to the corresponding 2-Deoxylactones by Lithium Iodide Trihydrate
Elliot, Russell P.,Fleet, George W. J.,Gyoung, Young Soo,Ramsden, Nigel G.,Smith, Colin
, p. 3785 - 3788 (1990)
Reaction of 2-O-trifluoromethanesulphonate esters of 1,4- and 1,5-α-hydroxy lactones with lithium iodide trihydrate in tetrahydrofuran gives good to excellent yields of the corresponding 2-deoxy lactones.
Highly enantioselective oxonium ylide formation and stevens rearrangement catalyzed by chiral Dirhodium(II) carboxamidates
Doyle, Michael P.,Ene, Doina G.,Forbes, David C.,Tedrow, Jason S.
, p. 4367 - 4370 (1997)
1,3-Dioxan-5-yl diazoacetates undergo conformation dependent oxonium ylide generation catalyzed by chiral dirhodium(II) carboxamidates, and Stevens rearrangement product(s) are formed with high chemoselectivity and with enantioselectivities reaching 88% ee.
