Tetrahedron Letters p. 4367 - 4370 (1997)
Update date:2022-08-10
Topics:
Doyle, Michael P.
Ene, Doina G.
Forbes, David C.
Tedrow, Jason S.
1,3-Dioxan-5-yl diazoacetates undergo conformation dependent oxonium ylide generation catalyzed by chiral dirhodium(II) carboxamidates, and Stevens rearrangement product(s) are formed with high chemoselectivity and with enantioselectivities reaching 88% ee.
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