130550-65-1

Upstream product

• 71769-39-6 (4R,5R,4'S)-5-Iodomethyl-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl] 
• 100-39-0 benzyl bromide 
• 74134-78-4 (2S,3R)-3,4-epoxy-1,2-O-isopropylidenebutane-1,2-diol 
• 114817-95-7 (R)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)prop-2-en-1-ol 

Downstream Products

• 104322-68-1 (2S)-benzyloxy-[(4S)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetaldehyde 
• 110009-21-7 (2R,3S)-1,2-epoxy-3-benzyloxy-4-pentene 
• 115586-66-8 (3R,4R)-3-O-benzyl-4,5-epoxy-1-penten-3-ol 
• 115483-06-2 (3S,4R)-3-O-benzyl-7-trimethylsilyl-1-hepten-6-yne-3,4-diol 
• 115483-07-3 (3R,4R)-3-O-benzyl-7-trimethylsilyl-1-hepten-6-yne-3,4-diol 
• 115483-08-4 (3S,4R)-3-O-benzyl-4-O-(tert-butyldimethylsilyl)-7-trimethylsilyl-1-hepten-6-yne-3,4-diol 
• 115483-09-5 (3R,4R)-3-O-benzyl-4-O-(tert-butyldimethylsilyl)-7-trimethylsilyl-1-hepten-6-yne-3,4-diol 
• 115483-05-1 (2R,3S)-3-O-benzyl-1-O-tosyl-4-pentene-1,2,3-triol 
• 115586-65-7 (2R,3R)-3-(benzyloxy)-2-hydroxypent-4-en-1-yl 4-methylbenzenesulfonate 
• 115483-13-1 (5R,6R,7R)-6-benzyloxy-7-(tert-butyldimethylsiloxy)-2-(trimethylsilyl)bicyclo<3.3.0>oct-1-en-3-one 
• 115483-14-2 (5S,6R,7R)-6-benzyloxy-7-(tert-butyldimethylsiloxy)-2-(trimethylsilyl)bicyclo<3.3.0>oct-1-en-3-one 
• 115483-11-9 (5R,6S,7R)-6-benzyloxy-7-(tert-butyldimethylsiloxy)-2-(trimethylsilyl)bicyclo<3.3.0>oct-1-en-3-one 
• 115483-12-0 (5S,6S,7R)-6-benzyloxy-7-(tert-butyldimethylsiloxy)-2-(trimethylsilyl)bicyclo<3.3.0>oct-1-en-3-one 
• 862972-77-8 (2R,3RS)-3-O-benzyl-4-pentene-1,2,3-triol 

Relevant academic research and scientific papers

Total synthesis of Berkeleylactone F

An efficient total synthesis of Berkeleylactone F has been synthesized from the known starting materials. The key steps involved in the synthesis are Wittig reaction, epoxide ring opening with 1, 3-dithiane and Yamaguchi macrolactonization.

Metal-graphite reagents in carbohydrate chemistry, IX. Fragmentations of 1-deoxy-1-iodo-2,3;4,5-di-O-isopropylidene pentitols

Compounds 1 and 3, each readily available in both enantiomeric forms smoothly fragment on treatment with zinc/silver-graphite or potassium-graphite laminate (C8K), respectively, thus affording the full set of stereoisomeric 1,2-O-isopropylidene-pent-4-enitols.