130571-48-1Relevant academic research and scientific papers
REARRANGEMENTS OF OPTICALLY ACTIVE CYCLOPROPYL ALLYL ESTERS BY LEWIS ACIDS AND PALLADIUM (0) CATALYSIS
Ollivier, Jean,Legros, Jean-Yves,Fiaud, Jean-Claude,Meijere, Armin de,Salauen, Jacques
, p. 4135 - 4138 (2007/10/02)
While optically active (1-siloxycyclopropyl) allyl esters underwent ready Lewis acids induced rearrangement into 2-vinylcyclobutanone with chirality transfer up to 71.5percent, Pd(0) failed for stereoelectronic reason to catalyse the expected C-3 -> C-4 r
