130613-89-7

Upstream product

• 1499-19-0 benzylphosphonic dichloride 
• 111525-41-8 (S)-4-N-tert-butylamino-2-butanol 
• 1024-41-5 benzyl tosylate 
• 141649-10-7 2-ethoxy-6-methyl-2-oxo-1,3,2-oxazaphosphorinane 

Downstream Products

• 130613-95-5 (2S,6S)-3-tert-Butyl-6-methyl-2-((R)-1-phenyl-pentyl)-[1,3,2]oxazaphosphinane 2-oxide 
• 130696-17-2 (2S,6S)-3-tert-Butyl-6-methyl-2-((S)-1-phenyl-pentyl)-[1,3,2]oxazaphosphinane 2-oxide 
• 130613-94-4 (2S,6S)-2-((S)-2-Benzyloxy-1-phenyl-ethyl)-3-tert-butyl-6-methyl-[1,3,2]oxazaphosphinane 2-oxide 
• 130696-16-1 (2S,6S)-2-((R)-2-Benzyloxy-1-phenyl-ethyl)-3-tert-butyl-6-methyl-[1,3,2]oxazaphosphinane 2-oxide 
• 130613-98-8 (2S,6S)-3-tert-Butyl-2-((R)-1,2-diphenyl-ethyl)-6-methyl-[1,3,2]oxazaphosphinane 2-oxide 
• 130696-20-7 (2S,6S)-3-tert-Butyl-2-((S)-1,2-diphenyl-ethyl)-6-methyl-[1,3,2]oxazaphosphinane 2-oxide 
• 130613-93-3 (2S,6S)-3-tert-Butyl-6-methyl-2-((R)-1-phenyl-ethyl)-[1,3,2]oxazaphosphinane 2-oxide 
• 130696-15-0 (2S,6S)-3-tert-Butyl-6-methyl-2-((S)-1-phenyl-ethyl)-[1,3,2]oxazaphosphinane 2-oxide 
• 130613-96-6 (R)-3-((2S,6S)-3-tert-Butyl-6-methyl-2-oxo-2λ⁵-[1,3,2]oxazaphosphinan-2-yl)-3-phenyl-propionic acid benzyl ester 
• 130696-18-3 (S)-3-((2S,6S)-3-tert-Butyl-6-methyl-2-oxo-2λ⁵-[1,3,2]oxazaphosphinan-2-yl)-3-phenyl-propionic acid benzyl ester 
• 130696-25-2 (1R)-(+)-1-phenethyl dimethylphosphonate 

Relevant academic research and scientific papers

Asymmetric electrophilic amination of chiral phosphorus-stabilized anions

The asymmetric electrophilic amination of phosphorus-stabilized anions derived from chiral oxazaphosphorinanes and diazaphospholidines is described. Trisyl azide is the reagent of choice for the amination process. The reaction is shown to be dependent on

Stereoselective Alkylations of Chiral, Phosphorus-Stabilized Benzylic Carbanions

A series of 6-substituted 2-benzyl-3-tert-butyl-1,3,2-oxazaphosphorinanes was prepared in racemic and enantiomerically pure form.The diastereoselectivity of alkylation of the derived anions was examined as a function of ring substitution pattern, base, so