130627-19-9Relevant academic research and scientific papers
Synthetic Routes to 1,5-Dihydro-5-oxo-4,1-benzoxazepines and to 5-Oxooxazoloquinolines
Gandhi, Sham S.,Bell, Karen L.,Gibson, Martin S.
, p. 13301 - 13308 (2007/10/02)
The literature concerning phenacyl anthranilate, N-phenacylanthranilic acid and phenacyl N-phenacylanthranilate is clarified.Phenacyl anthranilate is dehydrated to 1,5-dihydro-5-oxo-2-phenyl-4,1-benzoxazepine by treatment with phosphoryl chloride; other examples of this reaction are described.A preparation of 4-methyl-5-oxo-2-phenyloxazoloquinoline from N-phenacylanthranilic acid and propionic anhydride is reported.
Synthesis of 2-Substituted 1H-Benzoxazepin-5-ones
Sicker, Dieter
, p. 336 - 344 (2007/10/02)
An approach to the hitherto unknown class of 1H-benz>e>oxazepin-5-ones is given based on reduction and cyclization of appropriate acyclic ortho-nitro compounds as starting material.Thus, some 2-substituted derivatives (3a-i) were synthesized by catal
