130633-06-6

Basic information

• Product Name: 2-Buten-1-ol, 3-(4-methylphenyl)-
• CAS NO: 130633-06-6
• Molecular Formula: C11H14O
• Molecular Weight: 162.232
• Mol File: 130633-06-6.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: 2-Buten-1-ol, 3-(4-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Buten-1-ol, 3-(4-methylphenyl)-(130633-06-6)
• EPA Substance Registry System: 2-Buten-1-ol, 3-(4-methylphenyl)-(130633-06-6)

Safety Data

• Hazardous Substances Data: 130633-06-6(Hazardous Substances Data)

Upstream product

• 32147-13-0 3-(4-methylphenyl)-2-butenoic acid 
• 764-01-2 methyl propargyl alcohol 
• 5720-05-8 4-methylphenylboronic acid 
• 94853-53-9 ethyl 3-(4-methylphenyl)-2-butenoate 
• 51431-59-5 2-(p-tolyl)but-3-en-2-ol 
• 122-00-9 para-methylacetophenone 
• 6305-61-9 ethyl (E)-3-p-tolylbut-2-enoate 

Downstream Products

• 94853-56-2 3-methyl-3-(4-methylphenyl)-pent-4-enal 
• 140137-52-6 ethyl 3-methyl-3-(4-methylphenyl)-pent-4-enoate 
• 1310492-50-2 (2-methyl-2-(p-tolyl)cyclopropyl)methanol 
• 927833-56-5 4-methyl-4-(4-methylphenyl)-hepta-1,6-diene 
• 927833-58-7 1-methyl-4-(1-methylcyclopent-3-enyl)benzene 
• 1310492-51-3 C₁₃H₁₈O 
• 1310492-49-9 (2-methyl-2-(p-tolyl)cyclopropyl)methyl bromide 
• 65564-92-3 3-methyl-3-(4-methylphenyl)-cyclopentanone 
• 856177-23-6 (E)-3-(p-tolyl)-2-butenal 
• 1332645-31-4 (R)-4-(4-methylphenyl)-6-(trifluoromethyl)-6-phenyl-5,6-dihydro-2H-pyran-2-one 
• 1332645-32-5 (R)-4-(4-methoxylphenyl)-6-(trifluoromethyl)-6-phenyl-5,6-dihydro-2H-pyran-2-one 
• 106035-79-4 (R)-3-(4-methylphenyl)-1-butanol 
• 1238945-29-3 (S)-2-(p-tolyl)but-3-en-2-ol 
• 1461-10-5 (S)-3-(4-methylphenyl)-1-butanol 

Relevant articles and documents

Practical synthesis of aromatic bisabolanes: Synthesis of 1,3,5-bisabolatrien-7-ol, peniciaculin A and B, and hydroxysydonic acid

The enantioselective synthesis of aromatic bisabolanes, such as 1,3,5-bisabolatrien-7-ol, peniciaculin A and B, and hydroxysydonic acid, has been described. Our methodology for the total synthesis of aromatic bisabolanes involves the stereoselective const

NHC-catalyzed asymmetric α-regioselective [4 + 2] annulation to construct α-alkylidene-δ-lactones

The unprecedented NHC-catalyzed [4 + 2] annulation of α-bromoenals with dioxopyrrolidines is described. This protocol features broad substrate scope and allows rapid assembly of α-alkylidene-δ-lactones in good to high yields with excellent enantioselectivities. Notably, this process includes α-regioselective activation of azolium dienolate intermediates, which has not yet been reported.

Carbene-catalyzed enal γ-carbon addition to α-ketophosphonates for enantioselective access to bioactive 2-pyranylphosphonates

A carbene-catalyzed enantioselective [4+2] cycloaddition reaction between α,β-unsaturated aldehydes and α-ketophosphonates is developed. The reaction affords chiral 2-pyranylphosphonates with excellent enantioselectivities. The optically enriched phosphonate products bear multiple functional groups, including unsaturated lactone and phosphonate moieties that often lead to unique bio-activities. Preliminary studies show that the products from our reactions exhibit anti-bacterial (X. oryzae pv. oryzae) and anti-viral (Tobacco Mosaic Virus) activities for potential use in plant protection.